662-14-6Relevant academic research and scientific papers
FLUOROCARBON DERIVATIVES OF NITROGEN. PART 10. PREPARATION OF HEPTAFLUORO- AND 1-CHLOROHEXAFLUORO-2-NITROSOPROPANE, AND CONVERSION OF THE LATTER TO CHLOROPENTAFLUOROACETONE OXIME
Banks, Ronald E.,Dickinson, Neil,Morrissey, Alan P.,Richards, Adrian
, p. 87 - 92 (1984)
Details are given for the preparation of heptafluoro-2-nitrosopropane and 1-chlorohexafluoro-2-nitrosopropane via the routes CF3CF=CF2 ->FCO2Ag (RF = CF3, n-C3F7)> (CF3)2CFAg -> (with NOCl) (CF3)2CFNO and CF3CF=CF2 -> (with CsCl-NOCl) CF3(CF2Cl)CFNO, respectively, and for conversion of the latter nitroso-compound to chloropentafluoroacetone oxime via reduction with aqueous potassium hydrogen sulphite.
