FLUOROCARBON DERIVATIVES OF NITROGEN. PART 10. PREPARATION OF HEPTAFLUORO- AND 1-CHLOROHEXAFLUORO-2-NITROSOPROPANE, AND CONVERSION OF THE LATTER TO CHLOROPENTAFLUOROACETONE OXIME

DOI: 10.1016/S0022-1139(00)85122-2

Source and publish data:

Journal of Fluorine Chemistry p. 87 - 92 (1984)

Update date:2022-08-05

Topics:

Authors:

Banks, Ronald E.

Dickinson, Neil

Morrissey, Alan P.

Richards, Adrian

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Article abstract of DOI:10.1016/S0022-1139(00)85122-2

Details are given for the preparation of heptafluoro-2-nitrosopropane and 1-chlorohexafluoro-2-nitrosopropane via the routes CF3CF=CF2 ->FCO2Ag (R_F = CF3, n-C3F7)> (CF3)2CFAg -> (with NOCl) (CF3)2CFNO and CF3CF=CF2 -> (with CsCl-NOCl) CF3(CF2Cl)CFNO, respectively, and for conversion of the latter nitroso-compound to chloropentafluoroacetone oxime via reduction with aqueous potassium hydrogen sulphite.

Full text of DOI:10.1016/S0022-1139(00)85122-2

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