66217-71-8Relevant articles and documents
Diastereoselective addition of Di-(trimethylsilyl)phosphite to chiral N-(R)-α-methylbenzyl and N-(1-methoxycarbonyl-iso-pentyl) Schiff bases of various aldehydes
Lewkowski, Jaroslaw,Karpowicz, Rafal
experimental part, p. 326 - 331 (2011/04/16)
The addition of bis-(trimethylsilyl) phosphite to chiral imines of several aldehydes was diastereoselective. The separation of predominant diastereoisomers of a majority of formed aminophosphonic acids has been observed. Moreover, the ferrocene-derived ac
ASYMMETRIC ADDITION OF TRIS(TRIMETHYLSILYL) PHOSPHITE TO CHIRAL ALDIMINES
ZON, Jerzy
, p. 643 - 646 (2007/10/02)
Addition of tris(trimethylsilyl) phosphite (2) to (+)-(R)-1-phenylethylaldimines (1) and methanolysis of addition products affords(+)-N-(1-phenyethyl)-1-aminoalkanophosphonic acids (3).Chemical yields and diastereomeric composition of 3 vary from 10 to 90