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37714-05-9

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37714-05-9 Usage

General Description

(R)-1-Phosphono-benzylamine is a chemical compound with the molecular formula C8H11NO3P. It is an organophosphorus compound that contains a phosphorus atom bonded to a benzyl group. This chemical is commonly used as a ligand in metal-catalyzed reactions and as a building block in the synthesis of various pharmaceuticals and biologically active compounds. It has also been studied for its potential biological activities, including its use as an enzyme inhibitor for certain metabolic pathways. Due to its unique structure and functional groups, (R)-1-Phosphono-benzylamine holds promise for various applications in organic chemistry and medicinal chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 37714-05-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,7,7,1 and 4 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 37714-05:
(7*3)+(6*7)+(5*7)+(4*1)+(3*4)+(2*0)+(1*5)=119
119 % 10 = 9
So 37714-05-9 is a valid CAS Registry Number.

37714-05-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (R)-1-PHOSPHONO-BENZYLAMINE

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:37714-05-9 SDS

37714-05-9Relevant articles and documents

Double asymmetric induction during addition of chiral phosphites to C=N bond

Sheiko, Sergei,Guliaiko, Irina,Grushkun, Evgeni,Kolodiazhnyi, Oleg I.

, p. 2269 - 2270 (2002)

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Asymmetric synthesis of aminophosphonic acids

Miko?ajczyk, Marian,?yzwa, Piotr,Drabowicz, Józef

, p. 157 - 160 (1999)

A new synthesis of chiral α- and β-aminophosphonic acids is described which involves a highly diastereoselective addition of phosphite and phosphonate anions to enantiopure sulfinimines.

Highly diastereoselective addition of chiral H-phosphonate to tert-butylsulfinyl aldimines: a convenient approach to (R)-α-aminophosphonic acids

Olszewski, Tomasz K.,Majewski, Mateusz

, p. 846 - 852 (2015/08/18)

Abstract A highly diastereoselective nucleophilic addition of chiral H-phosphonate, derived from a readily available TADDOL auxiliary, to (S)-N-tert-butylsulfinyl aldimines is reported. The reaction proceeds at room temperature in the presence of potassium carbonate and yields the corresponding aliphatic, aromatic and heteroaromatic α-aminophosphonates with dr >95:5. Subsequent simultaneous removal of both chiral auxiliaries leads to the desired α-aminophosphonic acids in very good yields with an (R)-configuration at the stereogenic α carbon.

Biocatalyzed kinetic resolution of racemic mixtures of chiral α-aminophosphonic acids

Kozyra, Kinga,Brzezinska-Rodak, Malgorzata,Klimek-Ochab, Magdalena,Zymanczyk-Duda, Ewa

, p. 32 - 36 (2013/06/05)

Several fungal species namely: Aspergillus niger, Aspergillus parasiticus, Penicillium funiculosum, Trigonopsis variabilis and two different strains of Fusarium oxysporum were tested toward racemic mixtures of following phosphonic acids: 1-amino-2-methylp

1-(a-Aminobenzyl)-2-naphthol: A new chiral auxiliary for the synthesis of enantiopure a-aminophosphonic acids

Metlushka, Kirill E.,Kashemirov, Boris A.,Zheltukhin, Viktor F.,Sadkova, Dilyara N.,Buechner, Bernd,Hess, Christian,Kataeva, Olga N.,McKenna, Charles E.,Alfonsov, Vladimir A.

supporting information; experimental part, p. 6718 - 6722 (2010/02/28)

A new diastereoselective synthesis of a-aminophosphonates has been developed, based on the reaction, in the presence of trifluoroacetic acid, of trialkyl phosphites with chiral imines derived from (R)- or (S)-l-(ot- aminobenzyl)-2-naphthol. The reaction p

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