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CAS

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66228-00-0

Cyclohexanol, 3-methyl-2-(trimethylsilyl)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

66228-00-0

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66228-00-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 66228-00-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,6,2,2 and 8 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 66228-00:
(7*6)+(6*6)+(5*2)+(4*2)+(3*8)+(2*0)+(1*0)=120
120 % 10 = 0
So 66228-00-0 is a valid CAS Registry Number.

66228-00-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-methyl-cis-2-(trimethylsilyl)cyclohexanol

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:66228-00-0 SDS

66228-00-0Relevant articles and documents

Silanes in Organic Synthesis. 9. Enesilylation as a Method for 1,2-Carbonyl Migration within Ketones and for Conversion to 1,2-Transposed Allylic Alcohols

Fristad, William E.,Bailey, Thomas R.,Paquette, Leo A.

, p. 3028 - 3037 (2007/10/02)

Vinylsilanes are shown to be valuable synthetic intermediates in useful transformations of ketones.The epoxidation of vinylsilanes followed by lithium aluminium hydride reduction and oxidation with chromic acid and sulfuric acid in a two-phase (ether/water) system often gives high yields of 1,2-transposed ketones.With singlet oxygen and sequential sodium borohydride reduction, 2-trimethylsilyl alcohols are produced in which the α position of the parent ketone has been regiospecifically oxygenated.Fluoride ion promoted desilylation completes the conversion to the migrated allylic alcohol.

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