63031-68-5

Basic information

• Product Name: Silane, trimethyl(6-methyl-1-cyclohexen-1-yl)-
• CAS NO: 63031-68-5
• Molecular Formula: C10H20Si
• Molecular Weight: 168.354
• Mol File: 63031-68-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(6-methyl-1-cyclohexen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(6-methyl-1-cyclohexen-1-yl)-(63031-68-5)
• EPA Substance Registry System: Silane, trimethyl(6-methyl-1-cyclohexen-1-yl)-(63031-68-5)

Safety Data

• Hazardous Substances Data: 63031-68-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 52826-41-2 4-methyl-N'-(2-methylcyclohexylidene)benzenesulfonohydrazide 
• 56975-76-9 2-methylcyclohexanone benzenesulfonylhydrazone 
• 583-60-8 2-Methylcyclohexanone 

Downstream Products

• 21378-21-2 3-methylcyclohex-2-en-1-ol 
• 71352-17-5 3-methyl-2-(trimethylsilyl)cyclohex-2-en-1-ol 
• 73193-05-2 2-chloro-6-methylcyclohexanone 
• 591-24-2 3-Methylcyclohexanone 
• 73872-69-2 2-(trimethylsilyl)-3-methylcyclohexanone 
• 87842-56-6 4-(6-Methylcyclohexen-1-yl)butan-2-one 
• 66228-00-0 3-methyl-cis-2-(trimethylsilyl)cyclohexanol 
• 40648-10-0 1-Iodo-6-methylcyclohexene 

Relevant articles and documents

Silanes in Organic Synthesis. 8. Preparation of Vinylsilanes from Ketones and Their Regiospecific Cyclopentenone Annulation

A general method is described for the formation of vinylsilanes from ketones.Thus, conversion to the benzene- or p-toluenesulfonylhydrazone and sequential treatment with n-butyllithium and chlorotrimethylsilane in anhydrous tetramethylethylenediamine proceeds regiospecifically to afford the less substituted vinylsilane (in unsymmetrical cases).Friedel-Crafts acylation with acryloyl chlorides and aluminium chloride and subsequent Nazarov cyclization with Lewis acid catalysis results in cyclopentenone annulation.Numerous examples that reveal the scope of this processare described.Due to accompanying polymerization, annulation with acryloyl chloride itself is least efficient.This complication can, however, be averted through use of β-chloropropionyl chloride and dehydrochlorination with 1,5-diazabicycloundec-5-ene prior to ring closure.