66417-43-4

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 151-10-0 1,3-Dimethoxybenzene 
• 2785-97-9 (2,6-dimethoxyphenyl)lithium 

Downstream Products

• 68899-53-6 Benzyl-diphenyl-(2,6-dimethoxyphenyl)-phosphonium 
• 149639-58-7 (2,6-dimethoxyphenyl)diphenylphosphine oxide 
• 123317-13-5 C₂₀H₁₉O₂PSe 
• 67108-70-7 trans-di-iodobis(2,6-dimethoxyphenyldiphenylphosphine)platinum(II) 
• 67108-61-6 chloro(2,6-dimethoxyphenyldiphenylphosphine)[[2-(diphenylphosphino)-3-methoxyphenoxy]methyl-CP]platinum(II) 
• 67108-69-4 trans-dichlorobis(2,6-dimethoxyphenyldiphenylphosphine)platinum(II) 
• 67108-56-9 di-μ-chloro-bis[[[2-(diphenylphosphino)-3-methoxyphenoxy]methy]platinum(II)] 
• 67108-63-8 trans-dichlorobis(2,6-dimethoxyphenyldiphenylphosphine)palladium(II) 
• 67108-67-2 sym-trans-di-μ-chloro-bis[chloro(2,6-dimethoxyphenyldiphenylphosphine)palladium(II)] 
• 176207-48-0 (η(6)-hexamethylbenzene)RuCl[PPh2(2-O-C6H3-6-OMe)] 
• 211633-32-8 (η(5)-pentamethylcyclopentadienyl)RhCl2(η(1)-(2,6-dimethoxyphenyl)diphenylphosphine-P) 
• 211633-34-0 [(η(5)-pentamethylcyclopentadienyl)RhCl(η(2)-(2,6-dimethoxyphenyl)diphenylphosphine-P,O)]PF6 
• 250592-28-0 [(η(5)-pentamethylcyclopentadienyl)IrCl2((2,6-dimethoxyphenyl)diphenylphosphine-P)] 
• 228551-59-5 [(η(5)-pentamethylcyclopentadienyl)IrCl(Ph2PC6H3(O)OMe-2,6-κ(2)P,O)] 

Relevant academic research and scientific papers

Iron(ii)-catalysed [2+2+2] cycloaddition for pyridine ring construction

We report a new, simple and air-stable iron(ii) complex pre-catalyst for the synthesis of substituted pyridines via a [2+2+2] cycloaddition between diynes and nitrile derivatives. The Royal Society of Chemistry 2014.

A Highly Basic and Nucleophilic Triphenylphosphine, Tris(2,4,6-trimethoxyphenyl)phosphine, and Related Compounds

A series of methoxy substituted triphenylphosphines, R3-nPhnP , and their tertiary phosphonium perchlorates have been prepared.The basicity of the title compound, (1), in acetone was f

A Highly Basic Triphenylphosphine, 3P

Tris(2,4,6-trimethoxyphenyl)phosphine was found to be highly basic (pKa, 11.2).

PHOSPHORORGANISCHE VERBINDUNGEN 101. TERTIAERE PHOSPHINE MIT ORTHOALKOXYPHENYL-GRUPPEN. Synthese und Eigenschaften

Alkylphenylethers, ortho-lithiated in good yields, are transformed according to scheme (1) to the triarylphosphines ArPPh2, Ar2PPh and Ar3P (Ar contains in all cases an ortho-alkoxy group) (Table 1.).Hydroquinonedialkylethers can be lithiated twice, forming the compounds 102 and 103.Table 2 summarizes some arylalkylethers (71 - 101) which were lithiated; table 7 presents 12 new arylalkylethers.The syntheses of triarylphosphines with one or two bulky groups (105 - 110) and of triarylphosphines with one or two 3,4-dialkoxyphenyl groups (111 - 114) are reported.The 31P-spectra of the compounds prepared are discussed with respect to the validity of the Tolman-rule.