66428-69-1Relevant articles and documents
Syntheses of the marine metabolites verongamine, hemibastadin-2, and aerothionin using the cyano ylide coupling methodology
Wasserman, Harry H.,Wang, Jianji
, p. 5581 - 5586 (1998)
Syntheses of the marine metabolites verongamine, hemibastadin-2, and aerothionin have been accomplished by a methodology involving the conversion of a carboxylic acid to an acyl cyano phosphorane which may be oxidized to an α,β-diketo nitrile. This strong
Synthesis and structural revision of calafianin, a member of the spiroisoxazole family isolated from the marine sponge, Aplysina gerardogreeni
Ogamino, Takahisa,Nishiyama, Shigeru
, p. 1083 - 1086 (2007/10/03)
Calafianin 1 was successfully synthesized by employing a spiroisoxazoline compound, which was produced by electrochemical oxidation of the oximino-phenol derivative 7 followed by reduction. This investigation revealed a structural revision of 1, the trans
TOTAL SYNTHESES OF (+/-)-AEROTHIONIN AND (+/-)-HOMOAEROTHIONIN
Nishiyama, Shigeru,Yamamura, Shosuke
, p. 3351 - 3352 (2007/10/02)
Both aerothionin and homoaerothionin, the novel metabolites of the sponges Aplysina aerophoba, A. fistularis and Verongia thiona, have been synthesized in racemic form.