87580-08-3Relevant academic research and scientific papers
Total syntheses of (±)-aerothionin, (±)-homoaerothionin, and (±)-aerophobin-1
Nishiyama,Yamamura
, p. 3453 - 3456 (1985)
(±)-Aerothionin, (±)-homoaerothionin, and (±)-aerophobin-1 have been successfully synthesized using phenolic oxidation of the methyl pyruvate oxime derivative with thallium(III) trifluoroacetate as a key step. The stereostructure of aerophobin-2 has been also established by comparison of the 1H NMR spectrum with those of related compounds.
Electrochemical synthesis of spiroisoxazole derivatives and its application to natural products
Ogamino, Takahisa,Ishikawa, Yuichi,Nishiyama, Shigeru
, p. 73 - 78 (2007/10/03)
Efficient synthesis of the trans-spiroisoxazole (1) and its unnatural cis-isomer (2) was accomplished by employing anodic oxidation of 4, followed by Zn(BH4)2 reduction. This method was applied to an assembly of the carbon framework of zamamistatin (12).
