665002-73-3Relevant academic research and scientific papers
Synthesis and structure of an air-stable bis(isopropylcyclopentadienyl) zirconium perfluorooctanesulfonate and its catalyzed benzylation of 1,3-dicarbonyl derivatives with alcohols
Zhang, Xiaohong,Qiu, Renhua,Zhou, Congcong,Yu, Jingxing,Li, Ningbo,Yin, Shuangfeng,Xu, Xinhua
, p. 1011 - 1017 (2015/01/30)
An air-stable uninuclear complex of bis(isopropylcyclopentadienyl) zirconium perfluorooctane sulfonate (1a·H2O·3THF) was successfully synthesized by the reaction of (i-PrCp)2ZrCl2 with C17SO3Ag. The c
Benzylation of β-dicarbonyl compounds and 4-hydroxycoumarin using TMSOTf catalyst: A simple, mild, and efficient method
Theerthagiri, Palani,Lalitha, Appaswami
supporting information; experimental part, p. 5454 - 5458 (2010/11/02)
The direct benzylation of 1,3-dicarbonyl compounds and 4-hydroxycoumarin with a wide variety of benzylic alcohols was achieved using trimethylsilyl trifluoromethanesulfonate as an efficient catalyst. The reaction proceeded under very mild conditions at ro
FeCl2-catalyzed selective C-C bond formation by oxidative activation of a benzylic C-H bond
Li, Zhiping,Cao, Lin,Li, Chao-Jun
, p. 6505 - 6507 (2008/09/17)
(Chemical Equation Presented) Any old iron: Readily available and non-toxic FeCl2 effectively catalyzes C-C bond formation by oxidative activation of benzylic C-H bonds in the presence of tert-butyl peroxide as a stoichiometric oxidant (see sch
