66508-91-6Relevant academic research and scientific papers
Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'- trialkylhydrazinium salts
Shtamburg, Vasiliy G.,Shishkin, Oleg V.,Zubatyuk, Roman I.,Shtamburg, Victor V.,Tsygankov, Alexander V.,Mazepa, Alexander V.,Kadorkina, Gulnara K.,Kostyanovsky, Remir G.
, p. 289 - 291 (2013)
New types of 1,1,1-trialkyl-2-alkoxyhydrazinium chlorides and N-alkoxyhydrazines were obtained by reactions of N-chloro-N-alkoxy- ureas with trimethylamine or 1,4-diaza[2.2.2]bicyclooctane and by reactions of methyl N-chloro-N-methoxycarbamate with potass
Geminal systems: 64. N-alkoxy-N-chloroureas and N,N-dialkoxyureas
Shtamburg,Kostyanovsky,Tsygankov,Shtamburg,Shishkin,Zubatyuk,Mazepa,Kravchenko
, p. 62 - 75 (2015/10/05)
Molecular and crystal structures of N-alkoxy-N-chloroureas and N,N-dialkoxyureas were studied together with those of N-alkoxyureas as reference compounds. N-Alkoxy-N-chloroureas were found to have an elongated N - Cl bond and a shortened N-O(Alk) bond due to the nO(Alk)→σN-Cl anomeric effect. Alcoholysis of N-alkoxy-N-chloro derivatives of urea, N′-arylureas, and carbamates in the presence of silver trifluoroacetate leads to sterically hindered N,N-dialkoxyureas, N,N-dialkoxy-N′-arylureas, and N,N-dialkoxycarbamates, respectively.
