66623-67-4Relevant academic research and scientific papers
Electrochemically generated organothiating reagents and their use
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, (2008/06/13)
Electrolysis of organic disulfides in liquid sulfur dioxide is used to obtain organothiating agents, which can then be reacted with appropriate substrates to effect the synthesis of organothioaromatic compounds efficiently and in high yields. With appropriate phenolic compounds, regioselective substitution occurs in which para substitution greatly exceeds ortho substitution.
Electrochemical electrophilic aromatic methylthiation in liquid SO2
Glass, Richard S.,Jouikov, Viatcheslav V.
, p. 6357 - 6358 (2007/10/03)
Controlled potential electrolysis of dimethyldisulfide in liquid sulfur dioxide provides a strongly electrophilic methylthiating agent. This species methylthiates strongly to weakly activated arenes in good to excellent yield.
A reductive acidolysis final deprotection strategy in solid phase peptide synthesis based on safety-catch protection
Kimura, Tooru,Fukui, Toshio,Tanaka, Shigeki,Akaji, Kenichi,Kiso, Yoshiaki
, p. 18 - 26 (2007/10/03)
A reductive acidolysis final deprotection strategy in solid phase peptide synthesis was developed using a new safety-catch type of semi- permanent protecting groups and new linkers which were derived from 4- methylsulfinylbenzyl protection. This new strat
B12 Mimicry in a Weak Ligand Environment: Oxidation and Alkylation of Thiols
Chowdhury, Shantanu,Samuel, Purnima M.,Das, Indira,Roy, Sujit
, p. 1993 - 1994 (2007/10/02)
The first examples of alkylation and oxidation of thiols by cobalt in weakly coordinating ligand (MeCN) environments is presented as a mimic to B12-dependent nonenzymatic reaction.
A New Reductive Acidolysis Final Deprotection Strategy in Solid Phase Peptide Synthesis. Use of a New Safety-Catch Linker
Kiso, Yoshiaki,Fukui, Toshio,Tanaka, Shigeki,Kimura, Tooru,Akaji, Kenichi
, p. 3571 - 3574 (2007/10/02)
A new reductive acidolysis final deprotection strategy in solid phase peptide synthesis was developed using a new safety-catch linker; this new strategy was based on a two-dimensional protection scheme employing acid-labile temporary and acid-stable but reductive acidolysiscleavable semipermanent protecting groups.
