66716-63-0Relevant academic research and scientific papers
Synthesis of α-Phenylthio Enones and Esters of α-Phenylthio Alkenoic Acids
Durman, John,Grayson, J.Ian,Hunt, Paul G.,Warren, Stuart
, p. 1939 - 1946 (2007/10/02)
The title compounds can be made by a Pummerer dehydration from the corresponding saturated sulphoxides.The alkylation of anions from saturated and unsaturated ketones is described.
ALKYLATION OF EXTENDED ENOLATES FROM α-PHENYLTHIO CROTONATE ESTERS
Durman, John,Hunt, Paul G.,Warren, Stuart
, p. 2113 - 2116 (2007/10/02)
Conditions are described for the formation of enolate anions from substituted α-phenylthio-crotonate esters and their alkylation at the α-carbon atom.
Reactions of Benzenesulphenyl Chloride with α,β-Unsaturated Compounds: Part II - Role of Steric Factors on Stability of Intermediates
Bhongle, N. N.,Gogte, V. N.
, p. 632 - 636 (2007/10/02)
In presence of pyridine, benzenesulfphenyl chloride (1) adds on the methyl α- and β-methyl crotonates and methyl α- and β-methyl cinnamates (6-9) in regiospecific manner involving an onium intermediate such as (18).The product pattern is decided by the st
