667940-23-0

Basic information

• Product Name: 2-(3-bromophenyl)Naphthalene
• Synonyms: 2-(3-bromophenyl)Naphthalene;2-(3-broMophenyl)naphthale;2-(3-bromophenyl)phthalene
• CAS NO: 667940-23-0
• Molecular Formula: C₁₆H₁₁Br
• Molecular Weight: 283
• EINECS: 1592732-453-0
• Mol File: 667940-23-0.mol
• Article Data: 10

Chemical Properties

• Melting Point: 97.0 to 101.0 °C
• Boiling Point: 385.2±11.0 °C(Predicted)
• Appearance: /Solid
• Density: 1.381±0.06 g/cm3 (20 ºC 760 Torr)
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2-(3-bromophenyl)Naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-bromophenyl)Naphthalene(667940-23-0)
• EPA Substance Registry System: 2-(3-bromophenyl)Naphthalene(667940-23-0)

Safety Data

• Hazardous Substances Data: 667940-23-0(Hazardous Substances Data)

Upstream product

• 91-20-3 naphthalene 
• 1469819-22-4 C₁₂H₈Br₂I⁽¹⁺⁾*C₂F₃O₂^(1-) 
• 89598-96-9 (3-bromophenyl)boronic acid 
• 108-36-1 1,3-dibromobenzene 
• 32316-92-0 naphthalene-2-boronic acid 
• 591-18-4 1-Bromo-3-iodobenzene 

Downstream Products

• 667940-36-5 9-(2-naphthyl)-10-[3-(2-naphthyl)phenyl]anthracene 
• 176034-11-0 3‐(naphthalen‐2‐yl)aniline 
• 33104-32-4 β-(3-hydroxyphenyl)naphthalene 
• 870774-29-1 (3-(naphthalen-2-yl)phenyl)boronic acid 

Relevant articles and documents

Selective Mechanochemical Monoarylation of Unbiased Dibromoarenes by in Situ Crystallization

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of liquid, unbiased dibromoarenes under mechanochemical conditions selectively afford the monoarylated products. The lower reactivity of the crystalline monoarylated products relative to the liquid starting materials should be attributed predominantly to the low diffusion efficiency of the former in the reaction mixture, which results in a selective monoarylation. The present study sheds light on a novel approach using in situ phase transitions in solids to design selective organic transformations that are difficult to achieve via conventional solution-based synthesis.

Platinum-catalyzed C-H arylation of simple arenes

This report describes the Na2PtCl4 catalyzed C-H arylation of arene substrates with diaryliodonium salts. The site selectivity of these reactions is predominantly controlled by steric factors. Remarkably, Na2PtCl4-catalyzed naphthalene arylation proceeds with opposite site selectivity compared to that obtained with Na2PdCl 4 as the catalyst. Preliminary mechanistic studies provide evidence for a PtII/PtIV catalytic cycle involving rate-limiting C-C bond-forming reductive elimination.

PHENANTHRENE DERIVATIVE, AND MATERIAL FOR ORGANIC EL ELEMENT

A phenanthrene derivative is represented by a formula (1) below. In the formula (1), Ar1 and Ar2 each represent an aromatic hydrocarbon ring group having 6 to 18 carbon atoms for forming the ring. The aromatic hydrocarbon ring group contains none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. R1 represents a substituent, the number of which may be 0, 1 or more. R1 may be bonded in any position of the phenanthrene skeleton. n and m each represent an integer of 1 to 3. k represents an integer of 0 to 8.