669073-14-7Relevant academic research and scientific papers
Diastereoselective Reduction of Cyclopropenylcarbinol: New Access to anti-Cyclopropylcarbinol Derivatives
Zohar, Elinor,Marek, Ilan
, p. 341 - 343 (2004)
(Matrix presented) Cyclopropenylcarbinol derivatives are regio- and diastereoselectively reduced with LiAlH4 in Et2O into trans-cyclopropylcarbinols as a single isomer. The regioselectivity of the hydroalumination reaction on the cyclopropenyl ring has been mapped out by deuterium labeling experiments.
Cyclopropenylcarbinol derivatives as new versatile intermediates in organic synthesis: Application to the formation of enantiomerically pure alkylidenecyclopropane derivatives
Simaan, Samah,Masarwa, Ahmad,Zohar, Elinor,Stanger, Amnon,Bertus, Philippe,Marek, Ilan
supporting information; experimental part, p. 8449 - 8464 (2010/06/15)
The copper-catalyzed carbomagnesiation (or hydrometalation) reaction of chiral cyclopropenylcarbinol derivatives, obtained by means of a kinetic resolution of secondary allylic alcohols, leads to an easy and straightforward preparation of enantiomerically
