669081-18-9Relevant academic research and scientific papers
Trifluoroacetyl-Activated Nitrogen-Nitrogen Bond Cleavage of Hydrazines by Samarium(II) Iodide
Ding, Hui,Friestad, Gregory K.
, p. 637 - 640 (2007/10/03)
(Matrix presented) Trifluoroacetyl derivatives of hydrazines undergo clean and efficient reductive cleavage of the N-N bond with Sml2 in the presence of MeOH. After N-trifluoroacetylation, acyl-, aryl-, and alkyl-substituted hydrazines are redu
Asymmetric allylsilane additions to enantiopure N-acylhydrazones with dual activation by fluoride and In(OTF)3
Friestad,Ding
, p. 4491 - 4493 (2007/10/03)
A mild, convenient, and stereoselective addition of allylsilanes to enantiopure N-acylhydrazones occurs at room temperature upon complementary activation of both the allylsilane and the hydrazone (see scheme; OTf = trifluoromethanesulfonate). The reaction
