67038-61-3 Usage
General Description
"(1S)-1α-Iodo-2β-methoxycyclohexane" is a chemical compound that belongs to the class of cyclohexanes. It has a molecular formula of C7H13IO and a molecular weight of 248.08 g/mol. (1S)-1α-Iodo-2β-methoxycyclohexane is a derivative of cyclohexane, with an iodine atom and a methoxy group attached to different carbon atoms. It is commonly used in organic synthesis and pharmaceutical research due to its potential biological activities and therapeutic applications. The specific stereochemistry of this compound, with the (1S) configuration, makes it a valuable chiral building block for the synthesis of complex organic molecules. Furthermore, the presence of the iodine and methoxy groups in its structure adds to its potential as a valuable intermediate in the synthesis of various pharmaceuticals and agrochemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 67038-61-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,0,3 and 8 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 67038-61:
(7*6)+(6*7)+(5*0)+(4*3)+(3*8)+(2*6)+(1*1)=133
133 % 10 = 3
So 67038-61-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H13IO/c1-9-7-5-3-2-4-6(7)8/h6-7H,2-5H2,1H3
67038-61-3Relevant articles and documents
Hypervalent Iodine Compounds with Tetrazole Ligands
Kumar, Rajesh,Vaish, Avichal,Run?evski, Tom?e,Tsarevsky, Nicolay V.
, p. 12496 - 12506 (2018)
Hypervalent iodine compounds with two I-N bonds, containing 5-substituted tetrazoles as the ligands PhI(N4CR)2 (R = CH3, C6H5, and 4-CH3C6H4), were synthesized from PhI(O2CCF3)2 or PhICl2 and the corresponding tetrazole potassium salts. Alternatively, PhIO was reacted with the free tetrazoles, and the reactions afforded either PhI(N4CR)2 or, in most cases, μ-oxo- or oligomeric compounds with several I and O atoms in the backbone and two terminal tetrazole groups. The isolated compounds were reasonably stable in the solid state as well as in solution at room temperature but explosive at elevated temperatures (135-180 °C depending on the structure). The crystal structure of one representative compound (an oligomer with three I atoms in the backbone and 5-phenyltetrazole end groups) was solved and refined from synchrotron powder X-ray diffraction. The novel compounds were characterized by cyclic voltammetry and were found to be strong oxidants. In addition, they proved to be useful reagents for the iodotetrazolylation of unsaturated compounds such as styrene and cyclohexene and for the transfer of tetrazole groups to N,N-dimethylaniline.
