67057-49-2

Upstream product

• 18826-95-4 1.3-butanediol 
• 6955-57-3 phenylamidophosphoric dichloride 
• 31951-90-3 cis-2-chloro-2-oxo-4-methyl-1,3,2-dioxaphosphorinane 
• 62-53-3 aniline 
• 34875-40-6 (4-methyl-[1,3,2]dioxaphosphinan-2-yl)-phenyl-amine 
• 57579-04-1 ((2S,4R)-4-Methyl-2-thioxo-2λ⁵-[1,3,2]dioxaphosphinan-2-yl)-phenyl-amine 
• 57237-71-5 trans-2-anilino-4-methyl-1,3,2-dioxaphosphinane 2-selenide 
• 622-37-7 Phenyl azide 
• 16368-20-0 cis-2-hydro-2-oxo-4-methyl-1,3,2-dioxaphosphorinane 
• 57579-04-1 ((2S,4S)-4-Methyl-2-thioxo-2λ⁵-[1,3,2]dioxaphosphinan-2-yl)-phenyl-amine 
• 31951-90-3 2-chloro-2-oxo-2-mercapto-4-methyl-1,3,2-dioxaphosphorinane 
• 16727-61-0 2-hydroxy-2-oxo-4-methyl-1,3,2-dioxaphosphorinane 
• 42419-30-7 (2-methoxy-4c-methyl-2λ⁵-[1,3,2]dioxaphosphinan-2r-ylidene)-phenyl-amine 
• 42419-30-7 (2-methoxy-4t-methyl-2λ⁵-[1,3,2]dioxaphosphinan-2r-ylidene)-phenyl-amine 

Downstream Products

• 93-98-1 N-phenyl benzoyl amide 
• 108733-55-7 N-(4-methyl-2-oxo-1,3,2-dioxaphosphorinanyl)thiourea 
• 108733-55-7 N-(4-methyl-2-oxo-1,3,2-dioxaphosphorinanyl)thiourea 

Relevant academic research and scientific papers

Oxidation in organophosphorus chemistry: Potassium peroxymonosulphate

Potassium peroxymonosulphate (Oxone) is used as an efficient, chemoselective and stereoselective oxidizing agent for a wide variety of phosphorous, phosphothio- and phosphoseleno-compounds.

STEREOCHEMICAL ASPECTS OF THE REACTION OF DIALKYL PHOSPHATES WITH AMINE IN THE PRESENCE OF TRIPHENYLPHOSPHINE AND CARBON TETRACHLORIDE

Activation of P-chiral dialkyl phosphates with triphenylphosphine-carbon tetrachloride involves intermediate phosphonium salt 1 which undergoes nucleophilic attack by aniline or pyridine with inversion of configuration at the chiral phosphorus atom.

Cyclic Organophosphorus Compounds. Part 20. Structual Correlations in the 2-Amino-4-methyl-1,3,2-dioxaphosphinane Series. X-Ray Molecular Structure of cis-2-t-Butylamino-4-methyl-1,3,2-dioxaphosphinane 2-Oxide

The oxidation of cis-2-t-butylamino-4-methyl-1,3,2-dioxaphosphinane 2-selenide with hydrogen peroxide yields cis-2-t-butylamino-4-methyl-1,3,2-dioxaphosphinane 2-oxide.The oxide has been shown, by X-ray ananlysis, to exist in the chair form with the methy

Stereoretentive Conversion of Cyclic Phosphorothioates into Phosphates using Chloral

P-Chiral cyclic dialkyl phosphorothioates are converted into the corresponding P-chiral phosphates by chloral with retention of configuration at phosphorus.