6712-97-6

Upstream product

• 103-80-0 phenylacetyl chloride 
• 6921-34-2 benzylmagnesium chloride 
• 102-20-5 phenyl-acetic acid phenethyl ester 
• 105-58-8 Diethyl carbonate 
• 102-04-5 1,3-Diphenylpropanone 
• 541-41-3 chloroformic acid ethyl ester 
• 60-29-7 diethyl ether 
• 100-44-7 benzyl chloride 
• 71-43-2 benzene 
• 300-57-2 allylbenzene 
• 124-38-9 carbon dioxide 
• 110979-22-1 diethyl benzyl aluminum 
• 100-39-0 benzyl bromide 
• 616-38-6 carbonic acid dimethyl ester 

Downstream Products

• 50485-27-3 2-benzyl-1,3-diphenyl-1-propene 
• 4742-04-5 2-benzyl-1,3-diphenyl-propane 
• 4742-03-4 2-benzyl-2-bromo-1,3-diphenyl-propane 
• 1356013-82-5 1,3-di(cyclohexa-1,4-dienyl)-2-(cyclohexa-1,4-dienylmethyl)propan-2-ol 
• 84868-53-1 (2,2-dibenzyl-3-phenylpropyl)benzene 
• 4426-43-1 2,2,3,3-tetrabenzyl-1,4-diphenyl-butane 

Relevant academic research and scientific papers

Samarium-based Grignard-type addition of organohalides to carbonyl compounds under catalysis of CuI

Grignard-type additions were readily achieved under the mediation of CuI (10 mol%) and samarium (2 equiv.) by employing various organohalides,e.g.benzyl, aryl, heterocyclic and aliphatic halides (Cl, Br or I), and diverse carbonyl compounds (e.g.carbonic esters, carboxylic esters, acid anhydrides, acyl chlorides, ketones, aldehydes, propylene epoxides and formamides) to afford alcohols, ketones and aldehydes, respectively, with high efficiency and chemoselectivity, in which the organosamarium intermediate might be involved.

Ni-Catalyzed Formal Carbonyl-Ene Reaction of Terminal Alkenes via Carbon Dioxide Insertion

Nickel catalyzes the multicomponent coupling reaction of terminal alkenes, carbon dioxide, and organoaluminum reagents, leading to the synthesis of homoallylic alcohols in moderate-to-good yields with excellent regio- and stereoselectivities.

NOVEL VINYLBENZENE COMPOUND AND PHOTOSENSITIVE PHOTORESIST COMPOSITION COMPRISING THE SAME

Provided is a photocurable composition comprising: (A) a photocurable compound; and (B) a vinylbenzene-containing monomer having a structure represented by chemical formula 1. In the chemical formula 1, X, R1, R2, R3, L, L1, L2 and L3 are the same as defi

Hydrogen bonded arrays: The power of multiple hydrogen bonds

Hydrogen bond interactions in small covalent model compounds (i.e., deprotonated polyhydroxy alcohols) were measured by negative ion photoelectron spectroscopy. The experimentally determined vertical and adiabatic electron detachment energies for (HOCHsu

New coupling reactions of some acyl chlorides with samarium diiodide in the presence of samarium: Carbinols from three acyl units

A mixture of samarium(II) iodide and samarium can induce a coupling reaction of three molecules of alkanoyl halide to give trialkylcarbinols of 2-hydroxy-1,3-diones. When aliphatic, unbranched alkanoyl chlorides are used, this new coupling reaction provides trimeric products as the main reaction products. Tetrahydropyran (THP) proved superior as the solvent because no ring-opening and subsequent reaction with the alkanoyl halides was observed under the reaction conditions, unlike when THF was used. Wiley-VCH Verlag GmbH, 2000.

S,S-dimethyl dithiocarbonate: A novel carbonyl dication synthon in the synthesis of ketones

We report herein the use of DMDTC as an effective carbonyl dication equivalent in ketone synthesis. According to our strategy, we also successfully devised a synthetic pathway for S-methyl (trimethylsilyl)thioacetate which may be a potentially useful synthetic reagent in organic synthesis.

Synthesis, structural characterization, and reactivity of zirconium complexes containing trimethylenemethane-based ligands

General synthetic routes to zirconium metallocene-like complexes containing derivatives of the dianionic trimethylenemethane (TMM) ligand are presented. One approach consists of reacting the dilithium salts of TMM, tribenzylidenemethane (TBM), tert-butylt