67131-32-2Relevant academic research and scientific papers
Chiral silylation reagents: Determining configuration via NMR-spectroscopic coanalysis
Schroeder, Frank C.,Weibel, Douglas B.,Meinwald, Jerrold
, p. 3019 - 3022 (2004)
(Chemical Equation Presented) Derivatization with (+)- and (-)-chloromenthoxydiphenylsilane was used to determine the absolute configuration of the insect defensive agent pinoresinol (1). Although the 1H NMR chemical shift differences of the re
Chiral silylation reagents for the determination of absolute configuration by NMR spectroscopy
Weibel, Douglas B.,Walker, Tameka R.,Schroeder, Frank C.,Meinwald, Jerrold
, p. 2381 - 2383 (2007/10/03)
(equation presented) We have investigated the use of chiral silylating reagents as analytical probes for determining the absolute stereochemistry of natural products by NMR spectroscopy. These reagents are prepared in high chemical yield in one step and c
