67146-57-0

Basic information

• Product Name: 1,1'-dibenzyl-1,4,1',4'-tetrahydro-[4,4']bipyridinyl-3,3'-dicarboxylic acid diamide
• Synonyms: 1,1'-dibenzyl-1,4,1',4'-tetrahydro-[4,4']bipyridinyl-3,3'-dicarboxylic acid diamide
• CAS NO: 67146-57-0
• Molecular Weight: 426.518
• Mol File: 67146-57-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1,1'-dibenzyl-1,4,1',4'-tetrahydro-[4,4']bipyridinyl-3,3'-dicarboxylic acid diamide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-dibenzyl-1,4,1',4'-tetrahydro-[4,4']bipyridinyl-3,3'-dicarboxylic acid diamide(67146-57-0)
• EPA Substance Registry System: 1,1'-dibenzyl-1,4,1',4'-tetrahydro-[4,4']bipyridinyl-3,3'-dicarboxylic acid diamide(67146-57-0)

Safety Data

• Hazardous Substances Data: 67146-57-0(Hazardous Substances Data)

Upstream product

• 38661-88-0 (E)-1,2-diphenylbut-1-en-3-one 
• 30626-03-0 (3E)-4-(4-chlorophenyl)-3-buten-2-one 
• 952-92-1 1-Benzyl-1,4-dihydronicotinamide 
• 124-38-9 carbon dioxide 
• 3815-30-3 4-(4-methoxyphenyl)-3-buten-2-one 
• 624-49-7 dimethylfumarate 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 1896-62-4 (E)-benzalacetone 
• 624-48-6 dimethyl cis-but-2-ene-1,4-dioate 
• 108395-48-8 1-Benzyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenyl-ethyl)-1,4-dihydro-pyridine-3-carboxylic acid amide 
• 86668-17-9 1-Benzyl-4-[(4-cyano-phenyl)-hydroxy-methyl]-1,4-dihydro-pyridine-3-carboxylic acid amide 
• 86668-15-7 1-Benzyl-4-(hydroxy-phenyl-methyl)-1,4-dihydro-pyridine-3-carboxylic acid amide 
• 79430-99-2 (E)-methyl 4-(2-cyanovinyl)benzoate 
• 5096-13-9 1-benzylnicotinamide chloride 

Downstream Products

• 16183-83-8 1-benzyl-3-carbamoylpyridinium ion 
• 64534-99-2 Tetracyan-benzochinon, Radikalanion 
• 42439-31-6 tetrafluoro-p-benzosemiquinone radical anion 
• 103059-89-8 p-Bromanil-anionradikal 
• 113755-18-3 chloro-p-benzosemiquinone radical anion 
• 34537-54-7 2,6-dichloro-p-benzoquinone anion radical 
• 17217-66-2 p-chloranilate^(1-) 
• 3225-29-4 p-benzosemiquinone radical anion 
• 333786-12-2 (BNA)(Cp*Fe(CO)2) 
• 333786-10-0 (BNA)(CpFe(CO)2) 
• 20057-16-3 fully reduced 5-methylphenazinium 

Relevant articles and documents

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Selective H2 and CO production with rhenium(I) biscarbonyl complexes as photocatalyst

Rhenium(I) biscarbonyl complexes with two phosphine ligands photocatalyzed not only CO2 reduction under CO2 atmosphere but also H2 evolution under Ar. The reductant 1-benzyl-1,4-dihydronicotinamide (BNAH) worked only as a one-electron donor, and it was quantitatively converted to its corresponding oxidized dimer (BNA2). The photocatalytic reactions required addition of a base such as triethanolamine, because deprotonation from the oxidized BNAH (BNAH?+) is essential for the suppression of the back electron transfer from the reduced rhenium(I) complex to BNAH?+. 1H, 13C, and 31P NMR studies under vacuum or 13CO2 atmosphere indicated that the rhenium(I) complex is relatively stable under the CO2 reduction conditions, but it is converted to some other complexes under the H2 evolution conditions.

Semiconductor Photocatalysis: Effect of Light Intensity on Nanoscale CdS-Catalyzed Photolysis of Organic Substrates

The relationship between light intensity and product distribution in semiconductor photocatalysis was investigated by using nanoscale CdS microcrystallites (CdS-0) as photocatalysts, triethylamine (TEA) as the electron donor, and either aromatic ketones, electron-deficient alkenes, or 1-benzylnicotinamide (BNA+) as substrates.In the case of the ketones and BNA+, the yield of their respective one-electron reduction products, pinacols and the dimer, (BNA)2, increases with decreasing light intensity.When alkenes are employed in the CdS-0 system, cis-trans photoisomerization always occur regardless of the light intensity.The kinetics for the photocatalysis of the alkanes and the measuement of the inital formation rate of active lattice Cd atoms (Cd0) (which act as catalytic sites for two-electron-transfer reductions) reveal that Cd0 formation is proportional to the square of the relative light intensity, Ir2.The chemoselectivity in the photocatalysis using nanoscale CdS should be affected by the quantity of the Cd0, whose formation strongly depends on the light intensity.