67222-38-2Relevant academic research and scientific papers
Electrochemical Methoxylation of Allyl and Propenyl Derivatives of Phenol and Phenol Ethers
Barba, Isidoro,Chinchilla, Rafael,Gomez, Cecilia
, p. 3270 - 3272 (2007/10/02)
Anodic oxidation of a methanolic solution of a number of phenols and phenol ethers (anethole, estragole, safrole, isosafrole, eugenol, and isoeugenol) in a single cell at constant current, with use of sodium methoxide or sodium methoxide-sodium perchlorate as the supporting electrolyte, afforded substitution and addition products, some of them not described previously in the literature.
Anodic Oxidation of 4-Allyl-2,6-dimethoxyphenol and Related Compounds: Syntheses of Asatone and Related Neolignans
Nishiyama, Atsuko,Eto, Hideo,Terada, Yukimasa,Iguchi, Masanobu,Yamamura, Shosuke
, p. 2820 - 2833 (2007/10/02)
4-Allyl-2,6-dimethoxyphenol and related compounds have been subjected to anodic oxidation to afford a number of oxidation products including asatone-type neolignans, heterotropanone-type compounds and arylpropanoids.Furthermore, the formation processes of these oxidation products are shown to involve both radical and cationic reactions which are dependent upon the applied potentials, solvent media and substituents on the aromatic ring.Keywords - allylphenol; neolignan; electrochemical oxidation; Diels-Alder reaction; biomimetic synthesis
SYNTHETIC STUDIES ON ASATONE-TYPE NEOLIGNANS OXIDATION OF 4-ALLYLPHENOLS WITH THALLIUM (III) NITRATE
Niwa, Masatake,Noda, Hitoshi,Kobayashi, Hiroki,Yamamura, Shosuke
, p. 85 - 88 (2007/10/02)
Oxidation of 4-allylphenols in MeOH has been carried out using thallium (III) nitrate to give two different types of reaction product.In the cases of 4-allylphenols with an electron-donating group (MeO), methoxylation takes place on the aromatic ring resulting in the formation of asatone-type compound as well as of 2,5-cyclohexadien-1-one.In the case of 4-allyl-2-methoxy-6-nitrophenol, however, the allyl group was attacked by the reagent to give three phenols.
