672325-70-1Relevant articles and documents
Site-selective mono-oxidative addition of active zinc into carbon-bromine bond of dibrominated-thiophenes: Preparation of thienylzinc reagents and their applications
Jung, Hye-Soo,Cho, Hyun-Hee,Kim, Seung-Hoi
, p. 960 - 964 (2013/02/25)
A facile protocol for the preparation of 3-bromo-2-thienylzinc bromide A and 5-bromo-2-thienylzinc bromide B has been developed. It has been successfully accomplished by a site-selective oxidative addition of active zinc into a chemically pseudo-equivalent or equivalent carbon-bromine bond, respectively. The subsequent cross-coupling reactions of the organozincs were also successfully carried out under mild conditions providing the corresponding products in moderate to high yields.
A pentacyclic nitrogen-bridged thienyl-phenylene-thienyl arene for donor-acceptor copolymers: Synthesis, characterization, and applications in field-effect transistors and polymer solar cells
Tseng, Cheng-An,Wu, Jhong-Sian,Lin, Tai-Yen,Kao, Wei-Shun,Wu, Cheng-En,Hsu, So-Lin,Liao, Yun-Yu,Hsu, Chain-Shu,Huang, Huan-Yi,Hsieh, You-Zung,Cheng, Yen-Ju
, p. 2102 - 2110 (2012/10/29)
A pentacyclic benzodipyrrolothiophene (BDPT) unit, in which two outer thiophene rings are covalently fastened with the central phenylene ring by nitrogen bridges, was synthesized. The two pyrrole units embedded in BDPT were constructed by using one-pot pa