67233-91-4

Basic information

• Product Name: 9-Decenoic acid, ethyl ester
• Synonyms: 9-Decenoic acid, ethyl ester;ETHYLDEC-9-ENOATE;ethyl 9-decenoate
• CAS NO: 67233-91-4
• Molecular Formula: C₁₂H₂₂O₂
• Molecular Weight: 198.30
• Mol File: 67233-91-4.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 250.2 °C at 760 mmHg
• Flash Point: 100.8 °C
• Appearance: /
• Density: 0.88 g/cm³
• Vapor Pressure: 0.0219mmHg at 25°C
• Refractive Index: 1.438
• CAS DataBase Reference: 9-Decenoic acid, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Decenoic acid, ethyl ester(67233-91-4)
• EPA Substance Registry System: 9-Decenoic acid, ethyl ester(67233-91-4)

Safety Data

• Hazardous Substances Data: 67233-91-4(Hazardous Substances Data)

Usage

Definition

ChEBI: The fatty acid ethyl ester of dec-9-enoic acid.

InChI:InChI=1/C12H22O2/c1-3-5-6-7-8-9-10-11-12(13)14-4-2/h3H,1,4-11H2,2H3

Upstream product

• 6512-99-8 ethyl oleate 
• 74-85-1 ethene 
• 111-62-6 oleic acid ethyl ester 

Downstream Products

• 2388-81-0 11-oxo-hexadecanoic acid 
• 606142-98-7 (trans)-10-benzenesulfonyl-dec-9-enoic acid ethyl ester 
• 13019-22-2 9-Decen-1-ol 
• 112-30-1 1-Decanol 
• 1393378-48-7 dec-9-en-1-yl dec-9-enoate 
• 542-46-1 (Z)-civetone 
• 1192177-13-1 10-(2-fluoro-phenyl)-dec-9-enoic acid 
• 1192177-12-0 10-(2-fluoro-phenyl)-dec-9-enoic acid ethyl ester 
• 57-10-3 1-hexadecylcarboxylic acid 
• 95227-27-3 1,1-Diphenyl-decan-1,9-dien 

Relevant articles and documents

Improved preparation of an olefin metathesis catalyst bearing quaternary ammonium tag (FixCat) and its use in ethenolysis and macrocyclization reactions after immobilization on metal-organic framework (MOF)

An optimized synthesis of a key intermediate Ru4 in substantially improved yield of 50% and in scale up to 1 gram was described. Such obtained Ru4 was quantitatively converted into useful quaternary ammonium tagged catalyst Ru1 (FixCat) and immobilized in a metal-organic framework (MOF). Next, two challenging applications, not studied previously with hybrid Ru1@MOF catalyst were attempted. In the case of the RCM reaction yielding a macrocyclic musk lactone, heterogeneous Ru1@MOF exhibited under high-dilution conditions high resistance towards unwanted C-C double bond migration, thus offering superior selectivity as compared to analogous homogeneous catalysts. In ethenolysis of ethyl oleate, Ru1@MOF exhibited only slightly better selectivity as compared to well-known general-purpose Hoveyda-Grubbs SIMes and SIPr catalysts, while it was not able to challenge the benchmark Bertrand-Hoveyda-Grubbs catalyst in this transformation.

Specialized ruthenium olefin metathesis catalysts bearing bulky unsymmetrical NHC Ligands: Computations, synthesis, and application

Second-generation ruthenium olefin metathesis catalysts were investigated with systematic variation of the unsymmetrical uNHC ligands. Depending on the uNHC steric bulk, the catalysts exhibited different activity and selectivity in metathesis reactions. DFT calculations and X-ray crystallographic data were used to understand the influence of uNHC ligand structure on the catalyst properties. Furthermore, the catalysts were examined in the context of reactions that are problematic for general-purpose Ru catalysts, including industrially important self-cross metathesis of α-olefins and ethenolysis of ethyl oleate.

NOVEL RUTHENIUM COMPLEX, METHOD OF ITS PRODUCTION AND ITS USE IN REACTION OF OLEFINE METATHESIS

The invention relates to novel ruthenium complexes of formula (9). The invention also relates to the method for preparation of novel metal complexes of formula (9) and their use in olefin metathesis reactions.