67276-04-4Relevant articles and documents
Reaction of Trialkylboranes with Sodium Diethylhydroaluminate in the Presence of 1,4-Diazabicylooctane: a Convenient, General Method for Preparation of Sodium Trialkylhydroborates
Hubbard, John L.
, p. 1639 - 1640 (1989)
Trialkylboranes in tetrahydrofuran solution, even those with exceptionally large steric requirements, react readily with toluene solutions of sodium diethyldihydroaluminate in the presence of 1,4-diazabicyclooctane, resulting in a convenient and general preparation of sodium trialkylhydroborates.
Method for producing alkali metal monohydridoborates and monohydridoaluminates
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, (2008/06/13)
The invention relates to a method for producing compounds of general formula (A) by reacting an alkali metal hydride with a compound (B) during which the reaction is carried out in the presence of a catalyst that contains boron, whereby: M represents Li, Na, K, Rb or Cs; E represents B or Al, and; X1, X2, X3, independent of one another, represent a secondary or tertiary alkyl group, which is comprised of 2 to 10 atoms, or represent a phenyl group which itself can be alkyl-substituted or they represent an alkoxy group, and the catalyst, which contains boron, or the conversion product thereof with MH is capable of acting as a hydride transfer agent.