67281-38-3Relevant academic research and scientific papers
Enones from Acid Fluorides and Vinyl Triflates by Reductive Nickel Catalysis
Pan, Feng-Feng,Guo, Peng,Li, Chun-Ling,Su, Peifeng,Shu, Xing-Zhong
supporting information, p. 3701 - 3705 (2019/05/24)
A nickel-catalyzed reductive coupling between acid fluorides and vinyl triflates has been described. This method provides an efficient access to various enones and avoids the requirement for acyl or vinyl metallic reagents in the conventional approaches.
Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst
Lee, Dae-Yon,Moon, Choong Woon,Jun, Chul-Ho
, p. 3945 - 3948 (2007/10/03)
Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.
