67309-64-2Relevant academic research and scientific papers
Palladium/copper (I) halide catalyzed stereospecific couplings of 1,2- difluorovinylstannanes with aryl iodides and vinyl halides
Lu, Long,Burton, Donald J.
, p. 7673 - 7676 (1997)
Palladium/copper (1) halide catalyzed cross couplings of (E)- and (Z)- 1,2-difluorovinylstannanes with aryl iodides and vinyl halides proceeded at room temperature to stereospecifically give 1,2-disubstituted-1.2- difluoroolefins and 1.2-difluoro or 1,2,3
The stereospecific preparation of (E)-1,2-difluoro-1,2-disubstituted alkenes
Lu, Long,Burton, Donald J.
, p. 94 - 98,5 (2020/08/20)
(Z)-1,2-difluoro-2-substituted vinyl silanes were prepared stereospecifically from chlorotrifluoroethene, chlorotrimethylsilane and alkyl or aryllithium reagents. Subsequent exchange of the trimethylsilyl group via reaction of the vinylsilane with KF/n-Bu
REACTION OF α,β,β-TRIFLUOROSTYRENE WITH ARENEDIAZONIUM CHLORIDES. SYNTHESIS OF α,β-DIFLUOROSTILBENES
Ganushchak, N. I.,Bilaya, E. E.,Obushak, N. D.
, p. 298 - 300 (2007/10/02)
The reaction of α,β,β-trifluorostyrene with arenediazonium chlorides in the presence of copper(II) chloride as catalyst gave high yields of chloroarylation products 1-aryl-2-phenyl-1,2,2-trifluoro-3-chloroethanes.The regiospecificity of the reaction was c
