67356-86-9Relevant academic research and scientific papers
An entry to non-racemic β-tertiary-β-amino alcohols, building blocks for the synthesis of aziridine, piperazine, and morpholine scaffolds
Narczyk, Aleksandra,Stecko, Sebastian
, p. 5972 - 5981 (2020/08/21)
A method for the preparation of enantiopure β-tert-amino alcohols bearing a tetrasubstituted C-stereocenter, as well as their conversion into selected medicinally privileged heterocyclic systems (morpholines, aziridines, piperazines) is reported. These co
ALDOL-TYPE REACTIONS BETWEEN TRIMETHYLSILYL ENOL ETHERS AND ACETALS WITH THE AID OF RHODIUM COMPLEX
Sato, Susumu,Matsuda, Isamu,Izum, Yusuke
, p. 6657 - 6660 (2007/10/02)
Aldol type reactions of trimethylsilyl enol ethers with acetals, ketals and orthoesters are successfully performed with the aid of a catalytic amount of rhodium complex Rh4(CO)12 or (Rh(COD)(DPPB))(1+)*ClO4(1-), under neutral conditions.
PALLADIUM-CATALYZED ACYLATION OF ORGANOZINCS AND OTHER ORGANOMETALLICS AS A CONVENIENT ROUTE TO KETONES
Negishi, Ei-ichi,Bagheri, Vahid,Chatterjee, Sugata,Luo, Fen-Tair,Miller, Joseph A.,Stoll, A. Timothy
, p. 5181 - 5184 (2007/10/02)
The reaction of organozincs with acyl chlorides catalyzed by palladium-phosphine complexes, e.g., Pd(PPh3)4, provides a highly general and convinient route to ketones.
A NEW PROCEDURE FOR DESULFONYLATION: PREPARATION OF β-SUBSTITUTED α,β-UNSATURATED KETONES AND ALDEHYDES
Yoshida, Takashi,Saito, Shojiro
, p. 165 - 168 (2007/10/02)
The treatment of the tert-alkyl sulfones bearing carbonyl group at the β-position with 5 percent hydrochloric acid in THF at 30 - 65 deg C afforded β-substituted α,β-unsaturated ketones and aldehydes in excellent yields.
