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Upstream product

• 1066-35-9 dimethylmonochlorosilane 
• 779321-27-6 3,9,14,17-tetrahydroxy-1,3,5,7,9,11,14,16-octaphenyltricyclo[7.3.3^7,10]octasilsesquioxane 
• 18163-05-8 methallyl-dimethyl-silane 
• 15933-59-2 1,1,3,3-tetramethyldisilazane 

Relevant academic research and scientific papers

Tetra-functional double-decker silsesquioxanes as anchors for reactive functional groups and potential synthons for hybrid materials

A series of double-decker silsesquioxane derivatives with four reactive functional groups were designed, efficiently synthesized, and characterized. These novel inorganic-organic hybrids show highly attractive features for applications as building blocks

A Highly Effective Route to Si?O?Si Moieties through O-Silylation of Silanols and Polyhedral Oligomeric Silsesquioxane Silanols with Disilazanes

A simple and highly practical catalyst-free O-silylation of silanols with commercially available disilazanes has been developed under mild conditions. In the case of polyhedral oligomeric silsesquioxane (POSS) silanols and some other silanols, it was necessary to use catalytic amounts of inexpensive Bi(OTf)3 as additional catalyst. This efficient chlorine-free protocol involves the synthesis of a wide range of important organosilicon derivatives such as unsymmetrical disiloxanes and functionalized silsesquioxanes.

Highly Efficient Catalytic Route for the Synthesis of Functionalized Silsesquioxanes

Silsesquioxanes (POSS) have recently become the subject of growing interest in many branches of materials chemistry. Despite this great interest, no direct metal-catalyzed method to cap the corner of the POSS molecules has yet been proposed. In this report, we present a highly efficient method for the synthesis of functionalized silsesquioxanes mediated by scandium(III) triflate, which opens up the possibility of introducing a wide variety of functional groups into this class of organosilicon compounds under mild conditions with excellent yields. We also investigated the differences in the activity of the Lewis acid (Sc(OTf)3) and the hidden Br?nsted acid (TfOH) generated in situ from triflates as catalysts in the functionalization of silsesquioxanes. What is more, this solution provides an efficient corner-capping reaction and other functionalizations to obtain silsesquioxane derivatives which are often not possible to synthesize with good yields, efficiency, and chemoselectivity using conventional methods.

Silsesquioxane derivative and process for producing the same

The PSQ silsesquioxane derivative of the invention is represented by Formula (1), and it may be utilized as additives to ordinary organic polymers for improving the flame retardancy, heat resistance, weather resistance, light resistance, electric insulati

Silicon compound

The present invention provides a novel silicon compound represented by Formula (1) having a living radical polymerization initiating ability for addition-polymerizable monomers and a polymer obtained using the same. The above polymer can provide an organic-inorganic composite material having a distinct structure. wherein R1 is hydrogen, alkyl, aryl or arylalkyl; R2 and R3 are alkyl, phenyl or cyclohexyl; and A is a group having an ability to initiate polymerization of a monomer.