67460-34-8Relevant academic research and scientific papers
ASYMMETRIC SYNTHESIS OF OPTICALLY PURE α-METHYL-β,γ-UNSATURATED KETONES VIA TRIETHYLALUMINIUM-MEDIATED STEREOSPECIFIC PINACOL REARRANGEMENT OF ALKENYL GROUPS
Suzuki, Keisuke,Katayama, Eiji,Tsuchihashi, Gen-ichi
, p. 1817 - 1820 (1984)
Optically pure α-methyl-β,γ-unsaturated ketones are synthesized by the Et3Al-mediated pinacol-type rearrangement where alkenyl groups migrate stereospecifically with complete retention of the olefin-geometry.
Acyldemetallation of titanium(III) ?-allylic complexes
Kasatkin, A. N.,Kulak, A. N.,Tolstikov, G. A.
, p. 23 - 34 (2007/10/02)
Titanium(III) ?-allylic complexes, prepared by the interaction of 1,3-dienes or trienes with Cp2TiCl2 and n-PrMgBr, react with carboxylic acid chlorides RCOCl (R = alkyl, aryl, alkenyl) to give β, γ-unsaturated ketones in high yields.The reaction takes pl
