ASYMMETRIC SYNTHESIS OF OPTICALLY PURE α-METHYL-β,γ-UNSATURATED KETONES VIA TRIETHYLALUMINIUM-MEDIATED STEREOSPECIFIC PINACOL REARRANGEMENT OF ALKENYL GROUPS

DOI: 10.1016/S0040-4039(01)90049-8

Source and publish data:

Tetrahedron Letters p. 1817 - 1820 (1984)

Update date:2022-08-02

Topics:

Authors:

Suzuki, Keisuke

Katayama, Eiji

Tsuchihashi, Gen-ichi

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Article abstract of DOI:10.1016/S0040-4039(01)90049-8

Optically pure α-methyl-β,γ-unsaturated ketones are synthesized by the Et3Al-mediated pinacol-type rearrangement where alkenyl groups migrate stereospecifically with complete retention of the olefin-geometry.

Full text of DOI:10.1016/S0040-4039(01)90049-8

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