ASYMMETRIC SYNTHESIS OF OPTICALLY PURE α-METHYL-β,γ-UNSATURATED KETONES VIA TRIETHYLALUMINIUM-MEDIATED STEREOSPECIFIC PINACOL REARRANGEMENT OF ALKENYL GROUPS

DOI: 10.1016/S0040-4039(01)90049-8

Source and publish data:

Tetrahedron Letters p. 1817 - 1820 (1984)

Update date:2022-08-02

Topics:

Authors:

Suzuki, Keisuke

Katayama, Eiji

Tsuchihashi, Gen-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90049-8

Optically pure α-methyl-β,γ-unsaturated ketones are synthesized by the Et3Al-mediated pinacol-type rearrangement where alkenyl groups migrate stereospecifically with complete retention of the olefin-geometry.

Full text of DOI:10.1016/S0040-4039(01)90049-8

Products guided by the article

Product name:4-Penten-2-one, 3,4-dimethyl-1-phenyl-

Cas No:67460-34-8

R&D Labs maybe for 67460-34-8

Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Guangzhou Swan Chemical Co., Ltd.

Contact:+86-20-31075659

Address:NO.301, Hong ba fang investment BLDG 1,Guan chong village,Shiqi town,Panyu district,Guangzhou
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP

Relevant to this article

Discovery of aminobenzyloxyarylamides as κ opioid receptor selective antagonists: Application to preclinical development of a κ opioid receptor antagonist receptor occupancy tracer

Doi:10.1021/jm200789r
(2011)
A Non-Peptide NK₁ Receptor Agonist Showing Subpicomolar Affinity

Doi:10.1021/jm034219a
(2004)
Doi:10.1016/S0040-4039(01)94512-5
(1978)
Thermal dihydrogen elimination from Cp*₂Yb(4,5- diazafluorene)

Doi:10.1021/om300876b
(2013)
Design, Synthesis, and Biological Evaluation of Novel 1,3,4-Thiadiazolylpyrazolines Compounds Containing Ferrocene

Doi:10.1002/jhet.3238
(2018)
Discovery and SAR of Novel 2,3-Dihydroimidazo[1,2-c]quinazoline PI3K Inhibitors: Identification of Copanlisib (BAY 80-6946)

Doi:10.1002/cmdc.201600148
(2016)

Article Doi