Tetrahedron Letters p. 1817 - 1820 (1984)
Update date:2022-08-02
Topics:
Suzuki, Keisuke
Katayama, Eiji
Tsuchihashi, Gen-ichi
Optically pure α-methyl-β,γ-unsaturated ketones are synthesized by the Et3Al-mediated pinacol-type rearrangement where alkenyl groups migrate stereospecifically with complete retention of the olefin-geometry.
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