ASYMMETRIC SYNTHESIS OF OPTICALLY PURE α-METHYL-β,γ-UNSATURATED KETONES VIA TRIETHYLALUMINIUM-MEDIATED STEREOSPECIFIC PINACOL REARRANGEMENT OF ALKENYL GROUPS

DOI: 10.1016/S0040-4039(01)90049-8

Source and publish data:

Tetrahedron Letters p. 1817 - 1820 (1984)

Update date:2022-08-02

Topics:

Authors:

Suzuki, Keisuke

Katayama, Eiji

Tsuchihashi, Gen-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90049-8

Optically pure α-methyl-β,γ-unsaturated ketones are synthesized by the Et3Al-mediated pinacol-type rearrangement where alkenyl groups migrate stereospecifically with complete retention of the olefin-geometry.

Full text of DOI:10.1016/S0040-4039(01)90049-8

Products guided by the article

Product name:4-Penten-2-one, 3,4-dimethyl-1-phenyl-

Cas No:67460-34-8

R&D Labs maybe for 67460-34-8

shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Accela ChemBio Inc.

Contact:1-858-6993322

Address:9883 Pacific Heights Blvd., Suite H, San Diego
Henan zhongda Biological Engineering Co., Ltd

Contact:86-28-18109029985

Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK

Relevant to this article

Discovery of aminobenzyloxyarylamides as κ opioid receptor selective antagonists: Application to preclinical development of a κ opioid receptor antagonist receptor occupancy tracer

Doi:10.1021/jm200789r
(2011)
A Non-Peptide NK₁ Receptor Agonist Showing Subpicomolar Affinity

Doi:10.1021/jm034219a
(2004)
Doi:10.1016/S0040-4039(01)94512-5
(1978)
Thermal dihydrogen elimination from Cp*₂Yb(4,5- diazafluorene)

Doi:10.1021/om300876b
(2013)
Design, Synthesis, and Biological Evaluation of Novel 1,3,4-Thiadiazolylpyrazolines Compounds Containing Ferrocene

Doi:10.1002/jhet.3238
(2018)
Discovery and SAR of Novel 2,3-Dihydroimidazo[1,2-c]quinazoline PI3K Inhibitors: Identification of Copanlisib (BAY 80-6946)

Doi:10.1002/cmdc.201600148
(2016)

Article Doi