67519-00-0Relevant academic research and scientific papers
Oxygenation of Oleefinic Hydrocarbons Catalyzed by Iron(II) Acetonitrile Solvate
Kobayashi, Shigeki,Kotani, Eiichi,Ishii, Yoko,Tobinaga, Seisho
, p. 610 - 614 (2007/10/02)
Oxygenation reactions of olefins having an endo- or exo-cyclic double bond, namely, cyclohexene, norbornene, camphene, longifolene, and ent-kaurene, with a simple model reagent, Fe(MeCN)62+-H2O2-Ac2O, for mono-oxygenase were investigated in connection with their biotransformations.Keywords oxygenation; olefin; endo-cyclic double bond; exo-cyclic double bond; iron(II) acetonitrile solvate; hydrogen peroxide; model enzyme; mono-oxygenase
Chromic Acid Oxidation of Some Oxiranes
Krishna, R. R.,Chawla, H. P. S.,Dev, Sukh
, p. 1190 - 1196 (2007/10/02)
Oxiranes derived from some alkenes, with olefinic bonds present in different stereoelectronic environments, have been treated with Cr(VI)-reagents.The major products obtained have been identified and their formation rationalized.In some cases, the method becomes synthetically useful for C-C bond cleavage.
