15780-34-4

Upstream product

• 15780-45-7 (+/-)-1-(3,3-dimethyl-norborn-5-ene-2-endo-yl)-ethanone 
• 85506-67-8 endo-2,2-dimethylbicyclo<2.2.1>heptane-3-carboxylic acid 
• 917-54-4 methyllithium 
• 66062-78-0 1-((1S,4R)-3,3-Dimethyl-bicyclo[2.2.1]hept-2-yl)-ethanol 
• 38359-48-7 ω-methyl camphene 
• 141-79-7 4-methyl-pent-3-en-2-one 
• 542-92-7 cyclopenta-1,3-diene 
• 67-56-1 methanol 
• 92214-46-5 ω-iodo-ω-methylcamphene 
• 15780-34-4 1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon 
• 54382-52-4 (E)-3-ethylidene-2,2-dimethylbicyclo<2.2.1>heptane 
• 2226-05-3 2-(3,3-Dimethylbicyclo<2.2.1>hept-2-ylidene)ethanol 
• 6090-21-7 ω-bromomethylcamphene 
• 90275-75-5 ω-bromo-ω-methylcamphene 

Downstream Products

• 67519-00-0 2-exo-10-camphanoic acid 
• 15780-34-4 1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone 
• 66062-78-0 exo-1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol 
• 79861-75-9 1-(3,3-Dimethyl-2-exo-bicyclo<2.2.1>heptyl)-2-bromethanon 
• 515-28-6 (+/-)-2.2-Dimethyl-norbornanol-(3exo) 
• 78924-96-6 2-(3',3'-Dimethyl-2'-exo-norbornyl)-2-hydroxyessigsaeurebenzylester 
• 78925-02-7 ((1S,2R,4R)-3,3-Dimethyl-bicyclo[2.2.1]hept-2-yl)-hydroxy-acetyl chloride 
• 94201-14-6 4-(3,3-Dimethyl-2-exo-norbornyl)-2-methylbut-2-en-1-ol 
• 18310-55-9 (3,3-dimethylbicyclo[2.2.1]heptan-2-yl)methanol 

Relevant academic research and scientific papers

CONFORMATION-SPECIFIC PHOTOCHEMISTRY IN ISOTROPIC LIQUID MEDIA: NORRISH TYPE II REACTIONS OF EPIMERIC 2-ACETYL-3,3-DIMETHYL NORBORNANES

The epimeric ketones 1 and 2 have been shown to display conformation-specific photobehaviour, especially in liquid media.

Synthesis in the Isocamphane Series, XXIV. The Synthesis of endo-Configurated Isocamphane Derivatives

The syntheses of 46 endo-configurated isocamphane derivatives starting from camphenilanic acid (1) are described.The endo-configuration of the new compounds at position 2 of the bicyclus was retained throughout as has been established by 1H-NMR spectroscopy. - Keywords: Camphenilanic acid; Bicycloheptane; Aldol reaction; Grignard reaction; Enones

Photochemistry of Vinyl Halides: Part I - Radical Versus Ionic Photobehaviour of Some Vinyl Halides Based on Camphene

A systematic study of the photochemical behaviour of a group of vinyl halides (1-5) incorporating bicyclo(2.2.1)heptane skeleton is reported.The various parameters that control the formation of radical and ionic products have been investigated.The quenching and sensitization studies reveal that the radical products are derived from the triplet excited states whereas the corresponding singlet excited states may be responsible for the ionic products.The ground-state (silver ion-assisted) solvolytic reactivity pattern of these vinyl halides has been correlated for the first time with their photobehaviour.A plausible mechanism based on electron transfer concept has been proposed.