83438-75-9Relevant academic research and scientific papers
Chemical functionality of poly(methylenephosphine): Phosphine-borane adducts and methylphosphonium ionomers
Noonan, Kevin J. T.,Feldscher, Bastian,Bates, Joshua I.,Kingsley, Justin J.,Yam, Mandy,Gates, Derek P.
experimental part, p. 4451 - 4457 (2009/02/04)
The chemical functionality of poly(methylenephosphine) n-Bu[MesP-CPh 2]nH (2) is examined in reactions with two isoelectronic species, namely BH3 and CH3+. The potential reactivity of polymer 2 is mod
Molecular studies of the initiation and termination steps of the anionic polymerization of P=C bonds
Gillon, Bronwyn H.,Noonan, Kevin J.T.,Feldscher, Bastian,Wissenz, Jennifer M.,Kam, Zhi Ming,Hsieh, Tom,Kingsley, Justin J.,Bates, Joshua I.,Gates, Derek P.
, p. 1045 - 1052 (2008/09/16)
The initiation and termination steps of the anionic polymerization of P=C bonds have been modeled. The initiation step was investigated through the stoichiometric reaction of MesP=CPh2 (1) with RLi (R = Me or n-Bu). In each case, the addition w
A NUCLEOPHILIC REACTION OF A PHOSPHAALKENE: THE METHYLATION OF MESITYLDIPENYLMETHYLENEPHOSPHINE
Knaap, Th. A. van der,Bickelhaupt, F.
, p. 2037 - 2040 (2007/10/02)
The reaction of the title compound (1) with methyl iodide gives the ylide 3 and the phosphonium salt 4.The intermediate formation of the phosphoniaalkene 2 is postulated.
