67590-46-9Relevant academic research and scientific papers
Reactions of 4-alkyl-1-trityl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane cations with bases
Zhou, Yeping,Wroblewski, Andrzej E.,Verkade, John G.
, p. 183 - 206 (2007/10/03)
The syntheses of 4-alkyl-1-trityl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane tetrafluoroborates (alkyl group = Me, 4; Et, 5; t-Bu, 6) are described. Compounds 4, 5 and 6 in the presence of base (pyridine, DBU) or base (pyridine, DBU) plus H2O u
CYCLIC ORGANOPHOSPHORUS COMPOUNDS. PART XV. 4-t-BUTYL-2,6,7-TRIOXA-1-PHOSPHABICYCLOOCTANE AND ITS OXIDE
Edmundson, R. S.,Forth, C. I.
, p. 315 - 320 (2007/10/02)
Treatment of 4-t-butyl-2,6,7-trioxa-1-phosphabicyclooctane with sulphuryl chloride yields merely its P-oxide and not the expected 5-t-butyl-2-chloro-5-chloromethyl-1,3,2-dioxaphosphorinan 2-oxide.The mass spectra of the bicyclic phosphite and its oxide are discussed.
