67601-06-3

Basic information

• Product Name: [(3S,6R)-6-isopropenyl-3-methyl-dec-9-enyl] acetate
• Synonyms: (3S,6R)-3-Methyl-6-(prop-1-en-2-yl)dec-9-en-1-yl acetate
• CAS NO: 67601-06-3
• Molecular Formula: C₁₆H₂₈O₂
• Molecular Weight: 252.39
• Mol File: 67601-06-3.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 320.8°C at 760 mmHg
• Flash Point: 93.3°C
• Density: 0.879g/cm³
• Vapor Pressure: 0.00031mmHg at 25°C
• Refractive Index: 1.45
• CAS DataBase Reference: [(3S,6R)-6-isopropenyl-3-methyl-dec-9-enyl] acetate(CAS DataBase Reference)
• NIST Chemistry Reference: [(3S,6R)-6-isopropenyl-3-methyl-dec-9-enyl] acetate(67601-06-3)
• EPA Substance Registry System: [(3S,6R)-6-isopropenyl-3-methyl-dec-9-enyl] acetate(67601-06-3)

Safety Data

• Hazardous Substances Data: 67601-06-3(Hazardous Substances Data)

Upstream product

• 119614-84-5 (2S,5R)-5-Methanesulfonyloxymethyl-2,6-dimethyl-hept-6-enoic acid methyl ester 
• 7540-51-4 (S)-3,7-dimethyl-6-octen-1-ol 
• 73395-37-6 2,6-Dimethyl-2-hydroxy-8-((methoxyethoxy)methoxy)-3-octyl 2-Methoxy-2-trifluoromethylphenylacetate 
• 1117-61-9 (3R)-citronellol 
• 71256-71-8 (3RS,6RS)-6-(1-Hydroxy-1-methylethyl)-3-methyl-9-decen-1-yl Acetate 
• 150-84-5 citronellyl-acetate 
• 7086-79-5 (R)-4-methyl-3-(3'-oxobutyl)pent-4-enal 
• 82425-88-5 (R)-5-(2-hydroxyethyl)-6-methylhept-6-en-2-one 
• 132124-49-3 ((S)-6-Isopropenyl-3-methyl-dec-9-enyloxymethyl)-benzene 
• 75-36-5 acetyl chloride 
• 120040-94-0 methyl (3RS,6R)-3-methyl-6-(1-methylethenyl)-9-decenate 
• 120040-91-7 Methanesulfonic acid (R)-3-isopropenyl-hept-6-enyl ester 
• 120040-89-3 (R)-1,1-dimethoxy-3-(1-methylethenyl)-6-heptyne 
• 120040-90-6 (R)-3-(1-methylethenyl)-6-heptynal 

Relevant articles and documents

Efficient synthesis of the Aonidiella aurantii (Mask.) sex pheromone component: (3S,6RS)-3-methyl-6-(1-methylethenyl)-9-decenyl acetate

The title compound, active component of the sex pheromone of Aonidiella aurantii (California Red Scale), was synthesized in three steps starting from S-citronellyl acetate with a 30% overall yield. The key feature of the synthesis is a copper salt assisted, highly regioselective attack of the 4-butenyl bromide Grignard reagent on the γ-site of the chloroallylic system of (S)-8-chloro-3,7-dimethyl-6-octenyl acetate (8a).

A SIMPLE AND EFFICIENT SYNTHESIS OF 3-METHYL-6-(1-METHYLETHENYL)-9-DECEN-1-YL ACETATE A COMPONENT OF THE CALIFORNIA RED SCALE PHEROMONE

A diastereomeric mixture of (3S,6R) and (3S,6S) 3-methyl-6-(1-methylethenyl)-9-decen-1-yl acetate 1(a,b) has been synthesized in high yield starting from (S)-(-)-citronellol.The key step of the synthesis is the regioselective coupling of the benzothiazole

SYNTHESE DIASTEREOSELECTIVE D'UNE COMPOSANTE DE LA PHEROMONE SEXSUELLE DE "L'ECAILLE ROUGE DE CALIFORNIE" : L'ACETATE D'ISOPROPENYL-6 METHYL-3 DECENE-9 YLE(3S, 6R)

6-Isopropenyl 3-methyl 9-decene yl acetate (3S, 6R) has been synthesized from readily available trans(-)-dihydrocarvone.Regioselective ozonolysis of this ketone silyl enol ether is the key step of the sequence and allows to preserve both chiral centers.