67615-50-3Relevant academic research and scientific papers
Aldolases as leitmotiv - A nonenzymatic domino aldol reaction triggered by zinc bisenolate and polyenolate (ate) complexes
Schmittel,Ghorai
, p. 1992 - 1994 (2001)
A new zinc(II) mediated sequential aldol reaction is described for the diastereoselective one-pot synthesis of tetrahydropyran-2,4-diols. The dependence of the yield on the ratio Zn2+/enolate proposes that zinc(II) polyenolate and ate complexes may be involved.
Manganese(I) catalyzed cross-coupling of secondary allylic alcohols and primary alcohols
Pandia, Biplab Keshari,Pattanaik, Sandip,Gunanathan, Chidambaram
, (2021/11/01)
Cross-coupling of alcohols to value-added products by using sustainable catalytic reactions has gained attention in recent years. Isomerization of secondary allylic alcohol to the corresponding enolizable ketone is an atom economical and known transformation. Herein, a selective cross-coupling of secondary allylic alcohol and primary alcohol is reported to afford the corresponding α-alkenyl or alkylation products. These catalytic protocols proceed via acceptorless dehydrogenative coupling (ADC) or borrowing hydrogen (BH) strategies, which liberates water and/or hydrogen as the only byproducts. Highly abundant manganese-based pincer catalysts catalyze the reactions.
NUCLEOPHILIC SUBSTITUTION REACTION OF KETO-ALLYLIC SYSTEMS WITH A HETEROCYCLIC RING IN γ-POSITION
Zvak, Vladimir,Kovac, Jaroslav,Dandarova, Miloslava,Gracza, Tibor,Kriz, Miroslav
, p. 1764 - 1773 (2007/10/02)
Keto-allylic systems with a heterocyclic ring in γ-position were prepared; these undergo nucleophilic substitution reactions with amines, where a replacement of bromine at the bromomethyl group takes place in contrast to benzene analogues, where the nucle
