676486-15-0

Basic information

• Product Name: Sulfoxonium, dimethyl-, 2-(4-chlorophenyl)-2-oxoethylide
• CAS NO: 676486-15-0
• Molecular Formula: C10H11ClO2S
• Molecular Weight: 230.715
• Mol File: 676486-15-0.mol
• Article Data: 44

Chemical Properties

• CAS DataBase Reference: Sulfoxonium, dimethyl-, 2-(4-chlorophenyl)-2-oxoethylide(CAS DataBase Reference)
• NIST Chemistry Reference: Sulfoxonium, dimethyl-, 2-(4-chlorophenyl)-2-oxoethylide(676486-15-0)
• EPA Substance Registry System: Sulfoxonium, dimethyl-, 2-(4-chlorophenyl)-2-oxoethylide(676486-15-0)

Safety Data

• Hazardous Substances Data: 676486-15-0(Hazardous Substances Data)

Upstream product

• 1126-46-1 Methyl 4-chlorobenzoate 
• 5034-06-0 trimethyl sulfoxonium chloride 
• 1774-47-6 trimethylsulfoxonium iodide 
• 122-01-0 4-chloro-benzoyl chloride 

Downstream Products

• 1211-35-4 2-(4-chlorophenyl)-1H-indole 
• 1609939-52-7 3-(4-chlorophenyl)-2-methoxyisoquinolin-1(2H)-one 
• 21443-48-1 3,4-bis(4'-chlorobenzoyl)-1,2,5-oxadiazole-2-oxide 
• 27942-64-9 n-butyl 4-chlorobenzoate 
• 1195847-85-8 1-(4-chlorophenyl)-6-phenylhexane-1,5-dione 
• 937-20-2 p-chlorophenacyl chloride 
• 27052-20-6 (1-benzofuran-2-yl)(4-chlorophenyl)methanone 

Relevant articles and documents

Direct Synthesis of α-Fluoro-α-Triazol-1-yl Ketones from Sulfoxonium Ylides: A One-Pot Approach

The work reported herein showcases a new route to access α-fluoro-α-triazol-1-yl ketones from sulfoxonium ylides via α-azido-α-fluoro ketone intermediates. In a one-pot, two-step sequence, the ketosulfoxonium reactant initially undergoes insertion of F+ a

Hydroxyl-Directed Ruthenium-Catalyzed peri-Selective C-H Acylmethylation and Annulation of Naphthols with Sulfoxonium Ylides

Herein, we report a highly efficient ruthenium-catalyzed peri-selective C(sp2)-H acylmethylation of 1-naphthols with α-carbonyl sulfoxonium ylides by utilizing hydroxyl as a weakly coordinating directing group. This new method imparts good reactivity, excellent chemo- and regioselectivity, and broad functional group tolerance and involves mild reaction conditions. The C-H acylmethylated products can be readily cyclized into fluorescent annulated pyrans by a one-pot process.

Regioselective and Chemodivergent Synthesis of Azulenolactones and Azulenolactams from Rhodium(III)-Catalyzed Reactions of Azulenecarboxamides with Sulfoxonium Ylides

A regioselective and chemodivergent synthetic approach for azulenolactones and azulenolactams as a new scaffold was demonstrated through Rh(III)-catalyzed reaction of N-methoxyazulene-1-carboxamides with sulfoxonium ylides. Sulfoxonium ylides that act as a precursor of secondary carbene was described, leading to the selective formation of azulenolactones and azulenolactams bearing two substituents on a newly introduced double bond. This method demonstrated functionalization of less reactive 2-position of azulene to overcome the natural reactivity. (Figure presented.).