67663-78-9Relevant academic research and scientific papers
Synthesis and reactions of polymer-supported dicarbonyl(dienyl)(triphenylphosphine)iron(0) complexes
Siu, Anna F. H.,Kane-Maguire, Leon A. P.,Pyne, Stephen G.,Lambrecht, Richard H.
, p. 3747 - 3754 (1996)
A preparative method for novel polymer-supported Fe(η5-dienyl)(CO)2(PPh2-polystyrene) species from [Fe(η5-dienyl)(CO)3]+ (dienyl = C6H7, 2-MeOC6H6 or C7H9) cations has been developed. The polymer-supported complexes have been characterised by iron analysis and infrared and 31P NMR spectroscopic studies and shown to undergo nucleophilic attack on the dienyl ring in a similar fashion to that of their monomeric analogues. Treatment of the resultant adducts with trifluoroacetic acid regenerated the starting dienyliron polymers.
