
Journal of the Chemical Society, Dalton Transactions p. 3747 - 3754 (1996)
Update date:2022-07-30
Topics:
Siu, Anna F. H.
Kane-Maguire, Leon A. P.
Pyne, Stephen G.
Lambrecht, Richard H.
A preparative method for novel polymer-supported Fe(η5-dienyl)(CO)2(PPh2-polystyrene) species from [Fe(η5-dienyl)(CO)3]+ (dienyl = C6H7, 2-MeOC6H6 or C7H9) cations has been developed. The polymer-supported complexes have been characterised by iron analysis and infrared and 31P NMR spectroscopic studies and shown to undergo nucleophilic attack on the dienyl ring in a similar fashion to that of their monomeric analogues. Treatment of the resultant adducts with trifluoroacetic acid regenerated the starting dienyliron polymers.
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