67768-63-2

Usage

Uses

Used in Pharmaceutical Industry:
Methyl 2-methoxycyclohexa-2,5-diene-1-carboxylate is used as a key intermediate in the production of pharmaceuticals for its ability to facilitate the synthesis of complex organic molecules.
Used in Agrochemical Industry:
In the agrochemical industry, methyl 2-methoxycyclohexa-2,5-diene-1-carboxylate is utilized as a precursor in the synthesis of agrochemicals, contributing to the development of effective products for agricultural applications.
Used in Flavor and Fragrance Industry:
Methyl 2-methoxycyclohexa-2,5-diene-1-carboxylate is used as a flavor and fragrance ingredient due to its sweet, fruity aroma. It is frequently employed in the manufacturing of perfumes, soaps, and other personal care products to enhance their scent profiles.
Used in Fine Chemicals Industry:
methyl 2-methoxycyclohexa-2,5-diene-1-carboxylate is also used as an intermediate in the production of other fine chemicals, highlighting its versatility and importance in various chemical synthesis processes.

Upstream product

• 606-45-1 2-methoxybenzoic acid methyl ester 
• 67-56-1 methanol 
• 394656-01-0 (+/-)-2-methoxy-cyclohexa-2,5-diene-carboxylic acid ethyl ester 

Downstream Products

• 108162-04-5 2-Methoxy-1-(3-oxo-pentyl)-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 108161-89-3 2-Methoxy-1-(3-oxo-butyl)-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 52784-37-9 2-carbomethoxy-2-cyclohexenone 
• 141040-28-0 6-carbomethoxy-6-hydroxy-1-methoxy-1,4-cyclohexadiene 
• 140875-14-5 6-carbomethoxy-6-hydroxyperoxy-1-methoxy-1,4-cyclohexadiene 

Relevant academic research and scientific papers

A mild and effective method for the transesterification of carboxylic acid esters

An extraordinarily versatile transesterification of simple or highly functionalized esters of aliphatic and aromatic carboxylic acids in high yields is catalyzed by dibutyltin oxide [Eq. (1)]. The reaction is compatible with several functional groups, for example, acetals, ketals, aliphatic bromides, enol ethers, urethanes, as well as free hydroxy, phenolic, and amino groups, and even with water.

A general approach to the galanthamine ring system

An approach to the galanthamine ring system is reported, which utilises an intramolecular Heck reaction to establish the benzofuran ring system present in both galanthamine and morphine.

AN ECONOMICAL DIELS-ALDER STRATEGY FOR THE SYNTHESIS OF DAPHNIPHYLLUM ALKALOIDS

A convergent and essentially self-consistent strategy, featuring an unusual Diels-Alder reaction has been devised for the stereo-controlled synthesis of a logical tetracyclic precursor 21 to daphniphyllum alkaloids.

Organometallic Compounds in Organic Synthesis. Part 13. Stereoselectivity of Complexation of Cyclohexadiene Esters

Complexation of cyclohexadienes with Fe(CO)3 as the entering group are subject to classical steric hindrance by alkyl groups, but CO2R and related groups introduce a competing factor because they favour sterically the entering group, probably through an i