6779-11-9Relevant academic research and scientific papers
Synthesis and proton dissociation properties of arylphosphonates: A microwave-assisted catalytic arbuzov reaction with aryl bromides
Keglevich, Gyoergy,Gruen, Alajos,Boelcskei, Adrienn,Drahos, Laszlo,Kraszni, Marta,Balogh, Gyoergy T.
, p. 574 - 582 (2013/01/15)
A series of substituted diethyl arylphosphonates was synthesized by the microwave-assisted Arbuzov reaction of triethyl phosphite and aryl bromides in the presence of NiCl2 as the catalyst under solvent-free conditions in good yields. The resulting phosphonates were hydrolyzed to the corresponding arylphosphonic acids whose acidity was evaluated by physicochemical methods.
Oxidative heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids
Inoue, Atsushi,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 1484 - 1485 (2007/10/03)
Cleavage of a carbon-phosphorus bond is achieved under palladium catalysis in an oxidative Heck-type reaction which exploits arylphosphonic acids. The reaction of arylphosphonic acids with alkenes provides arylation products in good yields in the presence of TBAF with trimethylamine oxide as an oxidant. Copyright
