67808-80-4Relevant academic research and scientific papers
Highly regioselective palladium-catalyzed double hydroselenation of terminal alkynes with benzeneselenol in the presence of acetic acid
Ikeda, Takuma,Tamai, Taichi,Daitou, Masayuki,Minamida, Yoshiaki,Mitamura, Takenori,Kusano, Hiroki,Nomoto, Akihiro,Ogawa, Akiya
, p. 1383 - 1385 (2013/11/19)
Palladium diacetate (Pd(OAc)2), in the presence of acetic acid, is found to exhibit excellent catalytic activity for the double hydroselenation of terminal alkynes with benzeneselenol to yield the corresponding diselenoketals regioselectively.
METALLATION OF BENZYL SELENIDES AND OF α-ARYL SELENOACETALS. SCOPE AND LIMITATIONS.
Clarembeau, M.,Krief, A.
, p. 1723 - 1726 (2007/10/02)
α-Metallo benzylselenides and α-metallo selenoacetals derived from aromatic aldehydes have been conveniently prepared by metallation of the corresponding carbon acids.KDA in THF proved among the various basic systems tested, the most efficient.
A NOVEL METHOD FOR THE GEMINAL DIALKYLATION OF THE CARBONYL GROUP OF AROMATIC ALDEHYDES AND KETONES
Clarembeau, M.,Krief, A.
, p. 1719 - 1722 (2007/10/02)
The title transformation is efficiently achieved by using the selenium methodology which involves the sequential reductive alkylation of arylselenoacetals and of benzylselenides.
SYNTHESIS OF SELENOACETALS
Clarembeau, M.,Cravador, A.,Dumont, W.,Hevesi, L,Krief, A.,et al.
, p. 4793 - 4812 (2007/10/02)
This paper reports our results concerning the syntheses of various bis(alkylseleno)alkanes and some of their arylseleno analogues by different methods.The scope and limitation of each of them are presented.
