678149-54-7Relevant academic research and scientific papers
Total synthesis of enokipodins A-D and cuparene-1 ,4-diol
Srikrishna,Rao, M. Srinivasa
experimental part, p. 1363 - 1371 (2011/01/13)
A Claisen rearrangement and RCM reaction based sequence has been developed for total synthesis of the antifungal sesquiterpenes enokipodins A-D and cuparene-1 ,4-diol starting from 2,5-dimethoxy-4-methythydroquinone. Copyright
The first total synthesis of (±)-lagopodin A
Srikrishna,Vasantha Lakshmi,Ravikumar
, p. 1277 - 1281 (2007/10/03)
The first total synthesis of (±)-lagopodin A and a formal total synthesis of enokipodins A and B is described. The requisite precursors containing two vicinal quaternary carbon atoms were assembled employing Claisen rearrangement and an RCM reaction as ke
The First Total Synthesis of the Antimicrobial Sesquiterpenes (±)-Enokipodins A and B
Srikrishna,Rao, M. Srinivasa
, p. 374 - 376 (2007/10/03)
Efficient first total synthesis of antimicrobial sesquiterpenes enokipodins A and B (1 and 2, respectively) and formal total synthesis of cuparene-1,4-diol (5) and cuparene-1,4-quinone (7) have been accomplished starting from 2,5-dimethoxy-4-methyl-acetop
Baker's yeast-mediated enantioselective synthesis of the bisabolane sesquiterpenes (+)-curcuphenol, (+)-xanthorrhizol, (-)-curcuquinone and (+)-curcuhydroquinone
Fuganti, Claudio,Serra, Stefano
, p. 3758 - 3764 (2007/10/03)
Fermenting baker's yeast converts the unsaturated aldehydes 5a-c into the saturated alcohols 6a-c, respectively. The microbial saturation of substrates adsorbed on a nonpolar resin proceeds in high chemical yields and shows complete enantioselectivity in the formation of the (S)-(+) isomers. Enantiopure 6a-c are versatile chiral building blocks for the synthesis of bisabolane sesquiterpenes. Their usefulness is shown in the preparation of (S)-(+)-curcuphenol, (S)-(+)-xanthorrhizol, (S)-(-)-curcuquinone and (S)-(+)-curcuhydroquinone. The Royal Society of Chemistry 2000.
