67957-89-5

Upstream product

• 108-94-1 cyclohexanone 
• 87512-44-5 1-(diphenylphosphinoylmethyl)-7-oxabicyclo<4.1.0>heptane 
• 76002-40-9 1-(diphenylphosphinoylmethyl)cyclohexene 
• 87512-43-4 1-(diphenylphosphinoylmethyl)cyclohexanol 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 110452-14-7 2-phenylthiocyclohexanone 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 106813-33-6 4-(1-cyclohexenyl)-3-methylbutanol 
• 106813-31-4 1-(1-methylene-2-cyclohexyl)trans-2-buten-1-ol 
• 108970-02-1 1-(1-cyclohexenyl)-3-penten-2-ol 
• 79597-48-1 1-cyclohexenylmethyl phenyl sulfide 
• 67957-91-9 2-methyl-1-cyclohexenyl phenyl sulfide 
• 96921-49-2 1-exo-methylenecyclohex-2-yl(phenyl) sulfone 
• 864428-33-1 (2-methylene-1-pent-4-enylcyclohexanesulfonyl)benzene 

Relevant academic research and scientific papers

Allyl sulfones as precursors to allylzincs in the palladium-catalyzed zinc-ene cyclization: Highly efficient synthesis of enantiopure (-)-erythrodiene

(Chemical Equation Presented) Easily prepared allyl phenyl sulfones, capable of introduction of the alkene by electrophilic α-substitution, are superior to allyl acetates as substrates for Pd-catalyzed Zn-ene cyclizations, providing C5 or C4N r

REDUCTIVE METALLATION A GENERAL PREPARATIVE METHOD FOR HYDROCARBON ALLYLMETALLIC COMPOUNDS

Because of the great ease of preparation of allyl phenyl sulfides and their smooth reductive lithiation using lithium naphthalenide or 1-(dimethylamino)naphthalenide, these are ideal substrates for a particularly versatile preparative method for allylic a

Synthesis of an Unstable Allyl Sulphide from an Allyl Phosphine Oxide

The epoxide (8) reacts with PhSLi to give Horner-Wittig intermediate (9) and hence the allyl sulphide (10).The stereochemistry and reactions of the intermediates are described.