67957-89-5Relevant articles and documents
Allyl sulfones as precursors to allylzincs in the palladium-catalyzed zinc-ene cyclization: Highly efficient synthesis of enantiopure (-)-erythrodiene
Deng, Kai,Chalker, Justin,Yang, Ao,Cohen, Theodore
, p. 3637 - 3640 (2007/10/03)
(Chemical Equation Presented) Easily prepared allyl phenyl sulfones, capable of introduction of the alkene by electrophilic α-substitution, are superior to allyl acetates as substrates for Pd-catalyzed Zn-ene cyclizations, providing C5 or C4N r
Synthesis of an Unstable Allyl Sulphide from an Allyl Phosphine Oxide
Torr, Richard S.,Warren, Stuart
, p. 1169 - 1172 (2007/10/02)
The epoxide (8) reacts with PhSLi to give Horner-Wittig intermediate (9) and hence the allyl sulphide (10).The stereochemistry and reactions of the intermediates are described.