Tetrahedron Asymmetry p. 699 - 703 (2004)
Update date:2022-08-03
Topics:
Jia, Cai
Pearce, Alan J.
Bleriot, Yves
Zhang, Yongmin
Zhang, Li-He
Sollogoub, Matthieu
Sinay, Pierre
Trimethylaluminium induces a stereoselective rearrangement of unsaturated glycosides into polyfunctionalised cyclohexanic rings containing a tertiary alcohol and retaining the anomeric group. In contrast with the previously used triisobutylaluminium, no de-O-benzylation reaction was observed.
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(2004)
