68165-43-5

Basic information

• Product Name: Cyclohexanone, 3-hydroxy-3-methyl-
• CAS NO: 68165-43-5
• Molecular Formula: C7H12O2
• Molecular Weight: 128.171
• Mol File: 68165-43-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 3-hydroxy-3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 3-hydroxy-3-methyl-(68165-43-5)
• EPA Substance Registry System: Cyclohexanone, 3-hydroxy-3-methyl-(68165-43-5)

Safety Data

• Hazardous Substances Data: 68165-43-5(Hazardous Substances Data)

Upstream product

• 229638-75-9 3-hydroperoxy-3-methylcyclohexanone 
• 57256-12-9 1-methylcyclohexane-1,3-diol 
• 590-67-0 1-Methylcyclohexanol 
• 1193-18-6 3-methylcyclohexen-2-one 
• 21378-21-2 3-methylcyclohex-2-en-1-ol 
• 229638-71-5 5-methyl-bicyclo[3.1.0]hexan-1-ol 
• 21889-89-4 2,3-epoxy-3-methylcyclohexanone 
• 78-94-4 methyl vinyl ketone 
• 3332-08-9 2-isopropyliminopropane 

Downstream Products

• 1193-18-6 3-methylcyclohexen-2-one 
• 13505-34-5 2,6-heptandione 
• 57256-12-9 trans-1-methylcyclohexane-1,3-diol 
• 57256-12-9 (1RS,3SR)-1-methylcyclohexane-1,3-diol 
• 1558032-89-5 (R)-1-methyl-3-oxocyclohexyl benzoate 

Relevant articles and documents

Scalable, Electrochemical Oxidation of Unactivated C-H Bonds

A practical electrochemical oxidation of unactivated C-H bonds is presented. This reaction utilizes a simple redox mediator, quinuclidine, with inexpensive carbon and nickel electrodes to selectively functionalize "deep-seated" methylene and methine moieties. The process exhibits a broad scope and good functional group compatibility. The scalability, as illustrated by a 50 g scale oxidation of sclareolide, bodes well for immediate and widespread adoption.

Preparation of 2,3-epoxycycloalkanones from bicyclo[n.1.0]Alkan-1-ols

Copper- or iron-catalyzed oxidative rearrangement of bicyclo[n.1.0]alkan-1-ols yields 3-hydroperoxycycloalkanones and/or bicyclic peroxyhemiketals, which are transformed into 2,3-epoxycycloalkanones by treatment with a base.

Lithium naphthalenide induced reductive cleavage of α,β-epoxy ketones: An efficient procedure for the preparation of β-hydroxy ketones

Lithium naphthalenide presents itself as a mild and efficient reagent for the cleavage of α,β-epoxy ketones to give the corresponding β-hydroxy ketones in good yields.