68175-98-4

Upstream product

• 108-18-9 diisopropylamine 
• 532-55-8 Benzoyl isothiocyanate 
• 333-20-0 potassium thioacyanate 
• 98-88-4 benzoyl chloride 
• 540-72-7 sodium thiocyanide 

Downstream Products

• 942985-23-1 ReCl₂(triphenylphosphine)2(N,N-diisopropyl-N'-benzoylthioureato) 
• 1354044-66-8 [Co(III)(N-(diisopropylcarbamothioyl)benzamide(-H))3] 
• 942985-23-1 [ReCl₂(triphenylphosphine)2(N,N-diisopropyl-N'-benzoylthiourea(-1H))] 

Relevant academic research and scientific papers

Silica-gel-catalyzed conversion of stabilized phosphorus ylides to benzo[e][1,3]thiazocin derivatives

The reaction between triphenylphosphine, dialkylacetylenedicarboxylates, and N-benzoyl thiourea derivatives leads to intermediates such as vinyltriphenylphosphonium salts, which undergo Michael addition to produce the highly functionalized phosphorus ylid

N, N -Disubstituted- N ′-acylthioureas as modular ligands for deposition of transition metal sulfides

First row transition metal complexes (Ni, Co, Cu, Zn) with N,N-disubstituted-N′-acylthiourea ligands have been synthesized and characterized. Bis(N,N-diisopropyl-N′-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomp

Tris-chelate complexes of cobalt(III) with N-[di(alkyl/aryl)carbamothioyl] benzamide derivatives: Synthesis, crystallography and catalytic activity in TBHP oxidation of alcohols

New six coordinated tris-chelate cobalt(III) complexes of the type [Co(L)3] (1-4) {where HL = N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives}were prepared from the reaction between CoCl2· 6H2O and N-[di(alkyl/aryl)carbamothioyl]benzamide in ethanol and characterized by elemental analysis and spectral data (UV/Vis, IR, 1H & 13C NMR). The molecular structure of a representative complex [Co(L1)3] (1) [where HL1 = N-(diisopropylcarbamothioyl)benzamide], was determined by single crystal X-ray diffraction method and reveals a distorted octahedral geometry and a facial configuration of S atoms around the Co(III) center. These complexes act as efficient catalysts for the oxidation of alcohols to their corresponding aldehydes or ketones in presence of tert-butyl hydroperoxide (TBHP) at 80°C.

Efficient one-pot synthesis of alkyl 2-(dialkylamino)-4-phenylthiazole-5- carboxylates and single-crystal x-ray structure of methyl 2-(diisopropylamino)- 4-phenylthiazole-5-carboxylate

The reaction between secondary amines, benzoyl isothiocyanate, and dialkyl acetylenedicarboxylates (=dialkyl but-2-ynedioates) in the presence of silica gel (SiO2) led to alkyl 2-(dialkylamino)-4-phenylthiazole-5- carboxylates in fairly high yi