68191-22-0Relevant academic research and scientific papers
Metal-free in situ sp3, sp2, and sp C-H functionalization and oxidative cross coupling with benzamidines hydrochloride: A promising approach for the synthesis of α-ketoimides
Kalmode, Hanuman P.,Vadagaonkar, Kamlesh S.,Chaskar, Atul C.
, p. 60316 - 60326 (2015/02/19)
A new metal-free tandem protocol for the synthesis of α-ketoimides via sp3, sp2, and sp C-H functionalization followed by oxidative cross coupling with benzamidines hydrochloride using catalytic iodine with TBHP in DMSO has been developed. A wide range of functional group tolerance, an inexpensive catalyst, operational simplicity and good to excellent yields of the products are the striking features of this method.
Preparation of Aromatic Iodoacetyl Derivatives by Direct Iodination with a Potassium Iodide-Potassium Iodate-Sulfuric Acid System
Okamoto, Tsuyoshi,Kakinami, Takaaki,Nishimura, Tetsuo,Irwan-Hermawan,Kajigaeshi, Shoji
, p. 1731 - 1733 (2007/10/02)
The reaction of aromatic acetyl derivatives with potassium iodide and potassium iodate in acetic acid in the presence of sulfuric acid at room temperature gave iodoacetyl derivatives in good yields.
