68199-31-5

Basic information

• Product Name: (R)-N-(α-methylbenzylidene)-α-methylbenzylamine
• Synonyms: (R)-N-(α-methylbenzylidene)-α-methylbenzylamine
• CAS NO: 68199-31-5
• Molecular Weight: 223.318
• Mol File: 68199-31-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (R)-N-(α-methylbenzylidene)-α-methylbenzylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-(α-methylbenzylidene)-α-methylbenzylamine(68199-31-5)
• EPA Substance Registry System: (R)-N-(α-methylbenzylidene)-α-methylbenzylamine(68199-31-5)

Safety Data

• Hazardous Substances Data: 68199-31-5(Hazardous Substances Data)

Upstream product

• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 98-86-2 acetophenone 

Downstream Products

• 40648-92-8 (R,R)-(+)-bis[alpha-methylbenzyl]amine hydrochloride 
• 10024-74-5 (R,R)-N,N-bis-(1-phenylethyl)amine 
• 21003-57-6 (R,S)-bis(1-phenylethyl)amine 
• 1033190-52-1 C₁₈H₂₀BrNO 
• 1033190-51-0 C₂₂H₂₈N₃O₄P 
• 566930-72-1 4-methoxy-N,N-bis-(1-phenyl-ethyl)-benzamide 

Relevant articles and documents

Synthesis of α-methyl kainic acid by stereospecific lithiation-dearomatizing cyclization of a chiral benzamide

Stereospecific lithiation of N-α-methylbenzyl benzamides gives configurationally stable tertiary benzyllithiums which undergo a stereospecific dearomatizing cyclization with >99% retention of stereochemistry. The products are partially saturated isoindolinones which carry a new fully-substituted stereogenic centre. A ten-step sequence converts one of these products to the α-methyl analogue of kainic acid.

Practical asymmetric synthesis of β-trichloromethyl-β-hydroxy ketones by the reaction of chloral or chloral hydrate with chiral imines

(Matrix presented) Chloral or its hydrate undergoes the carbon-carbon bond-formation reaction with various optically active imines in the absence of any additive, followed by hydrolysis, to produce the corresponding β-trichloromethyl-β-hydroxy ketones in

NADH MODELS XXI. STEREOSELECTIVE REDUCTION OF CHIRAL IMINES WITH HANTZSCH ESTER

Imines derived from p-substituted acetophenones and (+) R-1-phenylethylamine are reduced by 3,5-diethoxycarbonyl-2,6-dimethyl-1,4-dihydro-pyridine (Hantzsch ester), in acetonitrile, in the presence of magnesium perchlorate, to diastereomeric mixtures of t